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Reversible reactions and equilibria

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Question 29

When iodine reacts with bromine, a compound forms.

The percentage composition by mass of this compound is:

I=34.6%Br=65.4% \text{I} = 34.6\% \quad \text{Br} = 65.4\% I=34.6%Br=65.4%
a.

Show, by calculation, that the empirical formula of this compound is IBr3\text{IBr}_3IBr3​.

[2]
b.

The molecular formula of this compound is I2Br6\text{I}_2\text{Br}_6I2​Br6​. I2Br6\text{I}_2\text{Br}_6I2​Br6​ is a dark red crystalline solid at room temperature and forms a liquid when heated. A dynamic equilibrium exists in this liquid, represented by this equation:

I2Br6(l)⇌IBr2+(l)+IBr4−(l) \text{I}_2\text{Br}_6(\text{l}) \rightleftharpoons \text{IBr}_2^+(\text{l}) + \text{IBr}_4^-(\text{l}) I2​Br6​(l)⇌IBr2+​(l)+IBr4−​(l)

(i) When a reaction is in dynamic equilibrium, the forward and backward reactions occur at the same time. State two other features of a reaction that is in dynamic equilibrium.

[2]
c.

Suggest why liquid I2Br6\text{I}_2\text{Br}_6I2​Br6​ conducts electricity, but solid I2Br6\text{I}_2\text{Br}_6I2​Br6​ does not.

[2]

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria