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Reversible reactions and equilibria

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Question 22

When a diatomic gas X2\text{X}_2X2​ is placed in a sealed flask, it dissociates to form a mononuclear gas X\text{X}X.

The equation for the reaction is

X2(g)⇌2X(g) \text{X}_2(\text{g}) \rightleftharpoons 2\text{X}(\text{g}) X2​(g)⇌2X(g) red-brown gas⇌colourless gas \text{red-brown gas} \rightleftharpoons \text{colourless gas} red-brown gas⇌colourless gas

A sample of pure X2\text{X}_2X2​ is placed in a sealed flask at 300 K300\text{ K}300 K. The flask is left until a dynamic equilibrium is reached.

a.

For a reaction that is in dynamic equilibrium, the forward and backward reactions occur at the same time.

State two other features of a reaction that is in dynamic equilibrium.

[3]
b.

At equilibrium, there is more X2\text{X}_2X2​ than X\text{X}X.

The graph shows how the amount of X2\text{X}_2X2​ in the sealed flask changes with time.

An equilibrium graph showing the amount of reactant X2 decreasing and leveling off to a plateau over time.

If you were to draw a cross (×\times×) on the graph to show the point where the reaction first reaches equilibrium, describe where it should be placed.

[1]
c.

Describe the start point, shape, and final level of the curve you would draw on the same graph to show how the amount of X\text{X}X in the sealed flask changes over the same time period.

[3]
d.

The sealed flask containing the equilibrium mixture is placed in a beaker of ice-cold water. The mixture becomes a deeper red-brown in colour.

Explain what this observation shows about the forward reaction.

[3]

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria