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Reversible reactions and equilibria

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Question 15

Methanol (CH3OH\text{CH}_3\text{OH}CH3​OH) is manufactured industrially from synthesis gas, which is a mixture of carbon monoxide and hydrogen.

The reaction is reversible and reaches a position of dynamic equilibrium.

CO(g)+2H2(g)⇌CH3OH(g)ΔH=−91 kJ/mol \text{CO}(\text{g}) + 2\text{H}_2(\text{g}) \rightleftharpoons \text{CH}_3\text{OH}(\text{g}) \qquad \Delta H = -91 \text{ kJ/mol} CO(g)+2H2​(g)⇌CH3​OH(g)ΔH=−91 kJ/mol

The industrial process is typically operated at a pressure of about 50 to 100 atmospheres and a temperature of 250∘C250^\circ\text{C}250∘C.

a.

State two features of a reaction that is in dynamic equilibrium.

[2]
b.

How would a decrease in temperature at constant pressure affect the amount of methanol in the equilibrium mixture? Explain your answer.

[2]
c.

How would an increase in pressure at constant temperature affect the amount of methanol in the equilibrium mixture? Explain your answer.

[2]
d.

Methanol (CH3OH\text{CH}_3\text{OH}CH3​OH) can be converted into methanal (HCHO\text{HCHO}HCHO). A mixture of methanol vapor and oxygen is passed over a heated copper catalyst. Methanal and water are the only products.

Write a chemical equation for this conversion of methanol into methanal.

[2]
e.

What is meant by the term catalyst?

[2]
f.

Explain how a catalyst works.

[2]
g.

Methanol can be used as a fuel. Write the chemical equation for the complete combustion of methanol.

[2]

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria