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Reversible reactions and equilibria

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Question 19

Carbonyl chloride (COCl2\text{COCl}_2COCl2​), commonly known as phosgene, is an extremely toxic gas used in industrial chemical synthesis.

a.

Carbonyl chloride is synthesized by reacting carbon monoxide with chlorine gas:

CO(g)+Cl2(g)⇌COCl2(g)ΔH=−108 kJ/mol \text{CO}(\text{g}) + \text{Cl}_2(\text{g}) \rightleftharpoons \text{COCl}_2(\text{g}) \quad \Delta H = -108\text{ kJ/mol} CO(g)+Cl2​(g)⇌COCl2​(g)ΔH=−108 kJ/mol

Explain why only a small yield of carbonyl chloride is obtained when the reaction is carried out at high temperatures.

[2]
b.

Predict and explain how the equilibrium yield of carbonyl chloride will change if the reaction pressure is increased.

[2]
c.

Carbonyl chloride reacts rapidly with water vapour to produce hydrochloric acid (HCl\text{HCl}HCl) and carbon dioxide. Write a balanced chemical equation for this hydrolysis reaction.

[2]
d.

The diagram below shows the displayed formula of carbonyl chloride:

Displayed formula of carbonyl chloride

Draw a dot and cross diagram to show the arrangement of all the outer electrons in a molecule of carbonyl chloride.

[2]

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria