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Reversible reactions and equilibria

Reversible reactions and equilibria

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Question 11

The equation for a reaction that occurs in the industrial oxidation of carbon monoxide is:

2CO(g)+O2(g)⇌2CO2(g)ΔH=−566 kJ/mol 2\text{CO}(g) + \text{O}_2(g) \rightleftharpoons 2\text{CO}_2(g) \quad \Delta H = -566 \text{ kJ/mol} 2CO(g)+O2​(g)⇌2CO2​(g)ΔH=−566 kJ/mol
a.

(i) State the meanings of the symbols ⇌ \rightleftharpoons\,⇌ and ΔH\Delta HΔH.

(ii) What does the negative sign of ΔH \Delta H\,ΔH indicate about the reaction?

[3]
b.

Describe how to complete an energy level diagram for this reaction, specifying the relative vertical positions of the lines for the reactants and the products.

[1]
c.

Typical conditions used for this reaction are a temperature of 450∘C450^\circ\text{C}450∘C and a pressure of 2 atm2\text{ atm}2 atm. Deduce the effects of changing the conditions as shown below (choose from the words increased, decreased or unchanged):

(1) Effect of an increase in temperature on the rate of reaction and on the yield of products;

(2) Effect of the addition of a catalyst on the rate of reaction and on the yield of products.

[4]
d.

A manufacturer considers using a pressure of 1 atm1\text{ atm}1 atm instead of 2 atm2\text{ atm}2 atm.

(i) Predict and explain the effect on the rate of reaction of changing the pressure to 1 atm1\text{ atm}1 atm.

(ii) Predict and explain the effect on the position of equilibrium of changing the pressure to 1 atm1\text{ atm}1 atm.

[4]
e.

Balance the equation representing the reduction of iron(III) oxide by carbon monoxide in a blast furnace:

…Fe2O3+…CO→…Fe+…CO2 \dots\text{Fe}_2\text{O}_3 + \dots\text{CO} \rightarrow \dots\text{Fe} + \dots\text{CO}_2 …Fe2​O3​+…CO→…Fe+…CO2​
[1]
Markscheme

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria

28 exam-style questions on Edexcel IGCSE Chemistry Reversible reactions and equilibria. Each one has a worked solution and a mark scheme showing where the marks go.

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