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Reversible reactions and equilibria

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Question 26

Ethene and steam are used in the industrial manufacture of ethanol (C2H5OH\text{C}_2\text{H}_5\text{OH}C2​H5​OH).

The reaction is reversible and can reach a position of dynamic equilibrium.

C2H4(g)+H2O(g)⇌C2H5OH(g)ΔH=−45 kJ/mol \text{C}_2\text{H}_4(\text{g}) + \text{H}_2\text{O}(\text{g}) \rightleftharpoons \text{C}_2\text{H}_5\text{OH}(\text{g}) \qquad \Delta H = -45 \text{ kJ/mol} C2​H4​(g)+H2​O(g)⇌C2​H5​OH(g)ΔH=−45 kJ/mol

The reaction is typically carried out at a pressure of about 60 atmospheres and a temperature of 300∘C300^\circ\text{C}300∘C.

a.

State two features of a reaction that is in dynamic equilibrium.

[2]
b.

How would an increase in temperature at constant pressure affect the amount of ethanol in the equilibrium mixture? Explain your answer.

[2]
c.

How would a decrease in pressure at constant temperature affect the amount of ethanol in the equilibrium mixture? Explain your answer.

[2]
d.

Ethanol (C2H5OH\text{C}_2\text{H}_5\text{OH}C2​H5​OH) can be converted into ethanal (CH3CHO\text{CH}_3\text{CHO}CH3​CHO). A mixture of ethanol and oxygen is passed over a heated silver catalyst. Ethanal and water are the only two products.

Write a chemical equation for this conversion of ethanol into ethanal.

[2]
e.

What is meant by the term catalyst?

[2]
f.

Explain how a catalyst works.

[2]
g.

Ethanol can be used as a biofuel. Write the chemical equation for the complete combustion of ethanol.

[2]

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria