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Reversible reactions and equilibria

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Question 14

The key reversible step in the industrial manufacture of sulfuric acid (the Contact Process) is represented by the following chemical equation:

2SO2(g)+O2(g)⇌2SO3(g) 2\text{SO}_2\text{(g)} + \text{O}_2\text{(g)} \rightleftharpoons 2\text{SO}_3\text{(g)} 2SO2​(g)+O2​(g)⇌2SO3​(g)
a.

Identify the industrial source from which each reactant is obtained:

  • Gas A (sulfur dioxide)
  • Gas B (oxygen)
[2]
b.

The graph shows the percentage yield of sulfur trioxide at equilibrium at different temperatures and pressures.

Percentage yield of sulfur trioxide at equilibrium (%) against Pressure (atm)

State the conditions of temperature and pressure from those shown on the graph that produce the largest percentage yield of sulfur trioxide.

[2]
c.

Find the percentage yield of sulfur trioxide at equilibrium at a pressure of 300 atm300\text{ atm}300 atm and a temperature of 450 ∘C450\ ^\circ\text{C}450 ∘C.

[1]
d.

Suggest why, in the actual industrial process, the percentage yield of sulfur trioxide per pass over the catalyst is lower than the equilibrium percentage yield at these conditions.

[1]

Reversible reactions and equilibria Questions

  1. IGCSE
  2. /Chemistry
  3. /Reversible reactions and equilibria