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Reversible reactions and equilibria

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Question 17

When iodine reacts with chlorine, a compound forms.

The percentage composition by mass of this compound is:

I=54.4%Cl=45.6% \text{I} = 54.4\% \quad \text{Cl} = 45.6\% I=54.4%Cl=45.6%
a.

Show, by calculation, that the empirical formula of this compound is ICl3\text{ICl}_3ICl3​.

[3]
b.

The molecular formula of this compound is I2Cl6\text{I}_2\text{Cl}_6I2​Cl6​. I2Cl6\text{I}_2\text{Cl}_6I2​Cl6​ is a bright yellow crystalline solid at room temperature and forms a liquid when heated. A dynamic equilibrium exists in this liquid, represented by this equation:

I2Cl6(l)⇌ICl2+(l)+ICl4−(l) \text{I}_2\text{Cl}_6(\text{l}) \rightleftharpoons \text{ICl}_2^+(\text{l}) + \text{ICl}_4^-(\text{l}) I2​Cl6​(l)⇌ICl2+​(l)+ICl4−​(l)

When a reaction is in dynamic equilibrium, the forward and backward reactions occur at the same time. State two other features of a reaction that is in dynamic equilibrium.

[2]
c.

Suggest why liquid I2Cl6\text{I}_2\text{Cl}_6I2​Cl6​ conducts electricity, but solid I2Cl6\text{I}_2\text{Cl}_6I2​Cl6​ does not.

[2]

Reversible reactions and equilibria Questions

  1. IGCSE
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  3. /Reversible reactions and equilibria