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Chemical formulae, equations and calculations

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Question 80

A student wants to find the value of xxx in hydrated copper(II) sulfate, CuSO4⋅xH2O\text{CuSO}_4 \cdot x\text{H}_2\text{O}CuSO4​⋅xH2​O.

She uses this method:

  • weigh an empty crucible to find its mass
  • place a sample of hydrated copper(II) sulfate crystals into the crucible and reweigh
  • heat the crucible gently
  • allow the crucible to cool and reweigh
  • repeat the process until the mass no longer changes (heating to constant mass)

The crystals decompose according to this equation:

CuSO4⋅xH2O→CuSO4+xH2O \text{CuSO}_4 \cdot x\text{H}_2\text{O} \rightarrow \text{CuSO}_4 + x\text{H}_2\text{O} CuSO4​⋅xH2​O→CuSO4​+xH2​O

These are the student's results:

  • Mass of empty crucible: 14.65 g14.65\text{ g}14.65 g
  • Mass of crucible and CuSO4⋅xH2O\text{CuSO}_4 \cdot x\text{H}_2\text{O}CuSO4​⋅xH2​O: 19.65 g19.65\text{ g}19.65 g
  • Mass of crucible and contents after heating to constant mass: 17.85 g17.85\text{ g}17.85 g
a.

State why it is necessary to heat the crystals to constant mass.

[1]
b.

Calculate the mass of CuSO4\text{CuSO}_4CuSO4​ formed after heating to constant mass.

[1]
c.

Calculate the mass of water lost from the crystals.

[1]
d.

Calculate the value for xxx in the formula CuSO4⋅xH2O\text{CuSO}_4 \cdot x\text{H}_2\text{O}CuSO4​⋅xH2​O. Give your answer to the nearest whole number.

[Mr of CuSO4=160;Mr of H2O=18] [M_r\text{ of }\text{CuSO}_4 = 160; M_r\text{ of }\text{H}_2\text{O} = 18] [Mr​ of CuSO4​=160;Mr​ of H2​O=18]
[3]
e.

When water is added back to the anhydrous copper(II) sulfate, the student observes that the mixture gets warm and changes colour from white to blue. Explain these observations.

[2]

Chemical formulae, equations and calculations Questions

  1. IGCSE
  2. /Chemistry
  3. /Chemical formulae, equations and calculations