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Chemical formulae, equations and calculations

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Question 39

The equation for the thermal dehydration of hydrated cobalt(II) chloride is:

CoCl2⋅6H2O(s)→CoCl2(s)+6H2O(g) \text{CoCl}_2\cdot 6\text{H}_2\text{O}(\text{s}) \rightarrow \text{CoCl}_2(\text{s}) + 6\text{H}_2\text{O}(\text{g}) CoCl2​⋅6H2​O(s)→CoCl2​(s)+6H2​O(g)

A student investigates the dehydration of hydrated cobalt(II) chloride using a crucible and lid heated on a clay pipe triangle.

She uses this method:

  • weigh the crucible, lid and hydrated cobalt(II) chloride
  • heat the crucible, lid and contents for 2 minutes
  • allow to cool and then reweigh
  • heat for a second period of 2 minutes
  • allow to cool and then reweigh
  • heat for a third period of 2 minutes
  • allow to cool and then reweigh

The table shows the student's results:

ExperimentMass before heating (g)Mass after heating for 2 minutes (g)Mass after heating for 4 minutes (g)Mass after heating for 6 minutes (g)
132.428.528.528.5
233.130.229.128.3
332.728.828.828.8
432.929.029.029.0
a.

Why does the mass decrease during heating?

[1]
b.

State the colours of the solids in the reaction:

  • CoCl2⋅6H2O(s)\text{CoCl}_2\cdot 6\text{H}_2\text{O}(\text{s})CoCl2​⋅6H2​O(s): __________
  • CoCl2(s)\text{CoCl}_2(\text{s})CoCl2​(s): __________
[2]
c.

In which experiment might the dehydration not be complete?

[1]
d.

Give a reason for your choice.

[1]
e.

Which statement could explain why the dehydration might not be complete?

  • A The student used a larger clay pipe triangle.
  • B The student used less hydrated cobalt(II) chloride than in the other experiments.
  • C The student used a gentle yellow Bunsen flame instead of a hot roaring blue flame.
  • D The student heated the crucible with the lid completely removed.
[1]
f.

In another experiment, the student calculates that she should obtain a mass of 5.2 g5.2\text{ g}5.2 g of CoCl2(s)\text{CoCl}_2(\text{s})CoCl2​(s) after completely dehydrating a sample of CoCl2⋅6H2O(s)\text{CoCl}_2\cdot 6\text{H}_2\text{O}(\text{s})CoCl2​⋅6H2​O(s). She actually obtains a mass of 4.6 g4.6\text{ g}4.6 g of CoCl2(s)\text{CoCl}_2(\text{s})CoCl2​(s). Calculate the percentage yield in her experiment. Give your answer to two significant figures.

[2]

Chemical formulae, equations and calculations Questions

  1. IGCSE
  2. /Chemistry
  3. /Chemical formulae, equations and calculations