An analytical chemist uses thin-layer chromatography (TLC) to determine the purity of an organic sample S S\,S and identify its components using three pure reference standards (XXX, YYY, and ZZZ). The resulting chromatogram is shown below.

Which statement is correct?
Sample SSS is a pure substance containing standard XXX, with an RfR_fRf value of 0.380.380.38.
Sample SSS is a mixture containing standards XXX and ZZZ, with RfR_fRf values of 0.380.380.38 and 0.750.750.75 respectively.
Sample SSS is a mixture containing standards XXX and ZZZ, with RfR_fRf values of 2.672.672.67 and 1.331.331.33 respectively.
Sample SSS is a pure substance containing standards XXX and ZZZ, with RfR_fRf values of 0.380.380.38 and 0.750.750.75 respectively.