Purity and separating mixtures

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Question 18
Medium
a.

A scientist investigates how fast four different solid pellets dissolve in an acidic solution. Each pellet has a different surface area. They add each pellet to 50 cm3 of dilute acid and measure the time taken for it to completely dissolve. The table shows their results:

PelletSurface area of pellet (cm2\text{cm}^2cm2)Volume of pellet (cm3\text{cm}^3cm3)Surface area to volume ratioTime taken to dissolve (seconds)
P3.60.49.0 : 148
Q2.20.211.0 : 139
R1.40.261
S4.80.316.0 : 1

Calculate the surface area to volume ratio of pellet R.

[1]
b.

A scientist investigates how fast four different solid pellets dissolve in an acidic solution. Each pellet has a different surface area. They add each pellet to 50 cm3 of dilute acid and measure the time taken for it to completely dissolve. The table shows their results:

PelletSurface area of pellet (cm2\text{cm}^2cm2)Volume of pellet (cm3\text{cm}^3cm3)Surface area to volume ratioTime taken to dissolve (seconds)
P3.60.49.0 : 148
Q2.20.211.0 : 139
R1.40.261
S4.80.316.0 : 1

Complete the sentence to describe the relationship between the surface area to volume ratio and the time taken to dissolve: "As the surface area to volume ratio increases, the pellet will take ______________ time to dissolve."

[1]
c.

A scientist investigates how fast four different solid pellets dissolve in an acidic solution. Each pellet has a different surface area. They add each pellet to 50 cm3 of dilute acid and measure the time taken for it to completely dissolve. The table shows their results:

PelletSurface area of pellet (cm2\text{cm}^2cm2)Volume of pellet (cm3\text{cm}^3cm3)Surface area to volume ratioTime taken to dissolve (seconds)
P3.60.49.0 : 148
Q2.20.211.0 : 139
R1.40.261
S4.80.316.0 : 1

The scientist thinks that pellet S will take the longest time to dissolve (dissolve slowest) in the acid. Explain why the scientist is incorrect.

[2]
d.

The scientist performs thin-layer chromatography (TLC) on a solution containing a chemical from pellet P.

The spots on the resulting chromatogram are colourless. State what the scientist could use to see the spots.

[1]
e.

The scientist performs thin-layer chromatography (TLC) on a solution containing a chemical from pellet P.

After using a technique to visualize the spots, the chromatogram for Pellet P is shown below:

A thin layer chromatogram showing a vertical ruler on the left, measuring from 0 cm to 9 cm with millimetre divisions. Adjacent to the ruler is a rectangular chromatography plate. Near the bottom of the plate, a horizontal dashed line labeled 'Pencil line' is aligned exactly with the 0 cm mark on the ruler. A cross is marked on this pencil line, labeled 'Pellet P' directly below it. A single prominent dark spot is located on the plate, with its center aligned with the 5.2 cm mark on the ruler. Near the top of the plate, a horizontal dashed line labeled 'Solvent front' is aligned exactly with the 8.0 cm mark on the ruler.

Calculate the Rf R_f\,Rf​ value for the spot seen from Pellet P. Show your working.

[2]

Purity and separating mixtures Questions

  1. GCSE
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