Purity and separating mixtures

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Question 13
Medium

A chemist uses thin-layer chromatography (TLC) to investigate three different herbal drink samples (AAA, BBB, and CCC) for the presence of organic acids.

Instead of a visual chromatogram, the chemist records the distance travelled by the solvent front and the individual substance spots:

  • Distance travelled by the solvent front = 8.0 cm8.0\text{ cm}8.0 cm
  • Sample AAA: spots at 3.6 cm3.6\text{ cm}3.6 cm and 6.4 cm6.4\text{ cm}6.4 cm
  • Sample BBB: a single spot at 3.6 cm3.6\text{ cm}3.6 cm
  • Sample CCC: spots at 1.2 cm1.2\text{ cm}1.2 cm, 4.8 cm4.8\text{ cm}4.8 cm, and 6.4 cm6.4\text{ cm}6.4 cm
a.

Explain what is meant by a pure substance in chemistry, and identify which sample (AAA, BBB, or CCC) is a pure substance based on these chromatography results.

[2]
b.

Calculate the RfR_fRf​ value of the spot that is common to both Sample AAA and Sample CCC.

[2]
c.

In another part of the investigation, the chemist determines the formulation of the herbal drink concentrate. An 18.2 g18.2\text{ g}18.2 g sample of the concentrate contains:

  • Citric acid: 2.4 g2.4\text{ g}2.4 g
  • Malic acid: 1.8 g1.8\text{ g}1.8 g
  • Water: 14.0 g14.0\text{ g}14.0 g

Calculate the percentage of citric acid in this concentrate formulation. Give your answer to 2 significant figures.

[2]

Purity and separating mixtures Questions

  1. GCSE
  2. /Chemistry
  3. /Purity and separating mixtures