Purity and separating mixtures

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Question 35
Medium

An analytical chemist uses thin-layer chromatography (TLC) to analyze three different plant-based dye extracts (Sample XXX, Sample YYY, and Sample ZZZ) for the presence of natural pigments.

Instead of viewing a visual chromatogram, the chemist records the distances travelled by the solvent front and the individual pigment spots:

  • Distance travelled by the solvent front = 12.0 cm
  • Sample XXX: spots at 5.4 cm and 11.4 cm
  • Sample YYY: a single spot at 5.4 cm
  • Sample ZZZ: spots at 3.3 cm, 7.2 cm, and 11.4 cm
a.

Explain what is meant by a pure substance in chemistry, and identify which sample (XXX, YYY, or ZZZ) is a pure substance based on these chromatography results.

[3]
b.

Calculate the Rf R_f\,Rf​ value of the pigment spot that is common to both Sample X X\,X and Sample ZZZ.

[2]
c.

In another part of the investigation, the chemist determines the composition of the dye concentrate. A 22.5 g sample of the concentrate contains:

  • Active pigment: 2.2 g
  • Stabiliser: 3.5 g
  • Water: 16.8 g

Calculate the percentage of active pigment in this concentrate formulation. Give your answer to 2 significant figures.

[2]

Purity and separating mixtures Questions

  1. GCSE
  2. /Chemistry
  3. /Purity and separating mixtures