An analytical chemist investigates the purity of four different organic samples that may contain salicylic acid. The literature melting point of pure salicylic acid is 159∘C159^\circ\text{C}159∘C.
SampleMelting point range (∘C)P159Q148−155R135S162−165 \begin{array}{|c|c|}\hline \textbf{Sample} & \textbf{Melting point range } (^\circ\text{C}) \\ \hline \text{P} & 159 \\ \hline \text{Q} & 148 - 155 \\ \hline \text{R} & 135 \\ \hline \text{S} & 162 - 165 \\ \hline \end{array} SamplePQRSMelting point range (∘C)159148−155135162−165Which statement is correct?
Sample R is impure salicylic acid.
Sample S is salicylic acid containing a small amount of impurity.
Sample Q is impure salicylic acid.
All four samples contain salicylic acid.