Kinetics

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Question 17
Easy

The Maxwell–Boltzmann distribution curves for a fixed mass of a gas at two different temperatures, TAT_{\text{A}}TA​ and TBT_{\text{B}}TB​, are shown below. The activation energy for a reaction is marked as EaE_{\text{a}}Ea​.

Maxwell-Boltzmann distribution curves at temperatures T_A and T_B

Which of the following statements is correct?

The total area under the curve for TAT_{\text{A}}TA​ is greater than that for TBT_{\text{B}}TB​ because a higher proportion of molecules are at lower kinetic energies.

The most probable kinetic energy of the molecules at TBT_{\text{B}}TB​ is lower than at TAT_{\text{A}}TA​, but a larger fraction of molecules have energy greater than or equal to EaE_{\text{a}}Ea​.

At temperature TBT_{\text{B}}TB​, the activation energy EaE_{\text{a}}Ea​ is reduced, allowing a larger proportion of molecules to react successfully.

The total area under each curve is identical, and at temperature TBT_{\text{B}}TB​, a larger fraction of molecules possess energy greater than or equal to EaE_{\text{a}}Ea​.

Kinetics Questions

  1. A Level
  2. /Chemistry
  3. /Kinetics