Kinetics

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Question 6
Easy

The Maxwell-Boltzmann energy distribution curves for a closed system containing a gas-phase mixture at two different temperatures, T1 T_1\,T1​ and T2T_2T2​, are shown.

Maxwell-Boltzmann energy distribution curves

Which of the following statements correctly identifies the relative temperatures and explains the primary reason for the increased rate of reaction at the higher temperature?

T2>T1T_2 > T_1T2​>T1​; the increase in reaction rate at T2T_2T2​ is primarily due to a significant increase in collision frequency.

T2>T1T_2 > T_1T2​>T1​; the increase in reaction rate at T2T_2T2​ is primarily because a much greater proportion of molecules have energy greater than or equal to EaE_aEa​, while EaE_aEa​ remains constant.

T1>T2T_1 > T_2T1​>T2​; the reaction rate is higher at T1T_1T1​ because the higher peak represents a greater proportion of reactant molecules colliding with the most probable energy.

T2>T1T_2 > T_1T2​>T1​; the increase in reaction rate at T2T_2T2​ is because the average kinetic energy of the particles is higher, which lowers the activation energy EaE_aEa​.

Kinetics Questions

  1. A Level
  2. /Chemistry
  3. /Kinetics