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Acids, alkalis and titrations

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Question 6

A student carries out a titration to find the concentration of a solution of sulfuric acid (H2SO4\text{H}_2\text{SO}_4H2​SO4​).

She is given:

  • a supply of the sulfuric acid solution of unknown concentration
  • potassium hydroxide (KOH\text{KOH}KOH) solution of concentration 0.150 mol/dm30.150\text{ mol/dm}^30.150 mol/dm3
  • apparatus suitable for carrying out a titration
  • phenolphthalein indicator

She uses this method to do the titration:

  • Step 1: add 20.0 cm320.0\text{ cm}^320.0 cm3 of the sulfuric acid solution to a conical flask
  • Step 2: add a few drops of phenolphthalein indicator to the conical flask
  • Step 3: fill a burette with the potassium hydroxide solution
  • Step 4: add the potassium hydroxide solution to the conical flask until the phenolphthalein indicator just changes colour
a.

Name the piece of apparatus that the student should use to add the sulfuric acid solution in step 1.

[1]
b.

What is the colour change of the phenolphthalein indicator in step 4?

  • A: colourless to pink
  • B: pink to colourless
  • C: orange to yellow
  • D: yellow to orange
[1]
c.

Why is it better to use phenolphthalein indicator rather than universal indicator in this titration?

[1]
d.

The student repeats the experiment four times to find the volume of KOH\text{KOH}KOH needed for neutralisation. The table shows her results:

Trial1234
Burette reading after adding potassium hydroxide solution (cm3\text{cm}^3cm3)23.1522.6522.8022.45
Burette reading before adding potassium hydroxide solution (cm3\text{cm}^3cm3)0.400.500.600.35
Volume of potassium hydroxide solution added (cm3\text{cm}^3cm3)22.7522.1522.2022.10

The average (mean) volume of potassium hydroxide solution should be calculated using only concordant results. Concordant results are those volumes that differ from each other by 0.20 cm30.20\text{ cm}^30.20 cm3 or less.

Calculate the average volume of potassium hydroxide solution added.

[2]
e.

In a different experiment under identical conditions, the student records the following titration results with another sample of sulfuric acid:

  • Volume of sulfuric acid solution added to conical flask: 20.0 cm320.0\text{ cm}^320.0 cm3
  • Concentration of potassium hydroxide solution: 0.150 mol/dm30.150\text{ mol/dm}^30.150 mol/dm3
  • Average volume of potassium hydroxide solution added from burette: 24.00 cm324.00\text{ cm}^324.00 cm3

The equation for the reaction is:

2KOH+H2SO4→K2SO4+2H2O 2\text{KOH} + \text{H}_2\text{SO}_4 \rightarrow \text{K}_2\text{SO}_4 + 2\text{H}_2\text{O} 2KOH+H2​SO4​→K2​SO4​+2H2​O

(i) Calculate the amount, in moles, of KOH\text{KOH}KOH in 24.00 cm324.00\text{ cm}^324.00 cm3 of the potassium hydroxide solution.

[1]
f.

(ii) Calculate the amount, in moles, of H2SO4\text{H}_2\text{SO}_4H2​SO4​ in the sulfuric acid solution.

[1]
g.

(iii) Calculate the concentration, in mol/dm3\text{mol/dm}^3mol/dm3, of the sulfuric acid.

[1]

Acids, alkalis and titrations Questions

  1. IGCSE
  2. /Chemistry
  3. /Acids, alkalis and titrations