A student performed a titration to find the concentration of a solution of sulfuric acid, H2SO4\text{H}_2\text{SO}_4H2SO4, using a standard solution of sodium hydroxide, NaOH\text{NaOH}NaOH.
The student repeated the titration of sulfuric acid solution with the sodium hydroxide solution and recorded these results:
| Run | 1 | 2 | 3 | 4 |
|---|---|---|---|---|
| Burette reading after adding alkali / cm3\text{cm}^3cm3 | 23.90 | 22.20 | 23.30 | 22.65 |
| Burette reading before adding alkali / cm3\text{cm}^3cm3 | 1.25 | 0.90 | 1.45 | 0.70 |
| Volume of alkali added / cm3\text{cm}^3cm3 | 22.65 | 21.30 | 21.85 | 21.95 |
The average (mean) volume of sodium hydroxide added should be calculated using only concordant results. Concordant results are those volumes that differ from each other by 0.10 cm30.10\text{ cm}^30.10 cm3 or less.
Identify the concordant results by stating which runs should be selected.
Calculate the average (mean) volume of sodium hydroxide added using your selected results.
The student used the same method to find the concentration of another sulfuric acid solution. The equation for the reaction is:
H2SO4+2NaOH→Na2SO4+2H2O \text{H}_2\text{SO}_4 + 2\text{NaOH} \rightarrow \text{Na}_2\text{SO}_4 + 2\text{H}_2\text{O} H2SO4+2NaOH→Na2SO4+2H2OThese are the student's experimental results:
The student used these results to calculate the concentration of the sulfuric acid solution:
There is one mistake in each step of the calculation. What correction should the student make in Step 1?
What correction should the student make in Step 2?
What correction should the student make in Step 3?