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Acids, alkalis and titrations

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Question 28

A student carries out a titration to find the concentration of a solution of oxalic acid (H2C2O4\text{H}_2\text{C}_2\text{O}_4H2​C2​O4​).

She is given:

  • a supply of the oxalic acid solution of unknown concentration
  • sodium hydroxide (NaOH\text{NaOH}NaOH) solution of concentration 0.120 mol/dm3
  • apparatus suitable for carrying out a titration
  • phenolphthalein indicator

She uses this method to do the titration:

  • Step 1: add 25.0 cm3 of the oxalic acid solution to a conical flask
  • Step 2: add a few drops of phenolphthalein indicator to the conical flask
  • Step 3: fill a burette with the sodium hydroxide solution
  • Step 4: add the sodium hydroxide solution to the conical flask until the phenolphthalein indicator just changes colour
a.

Name the piece of apparatus that the student should use to add the oxalic acid solution in step 1.

[1]
b.

What is the colour change of the phenolphthalein indicator in step 4?

  • A: pink to colourless
  • B: colourless to pink
  • C: yellow to red
  • D: red to yellow
[1]
c.

Why is it better to use phenolphthalein indicator rather than universal indicator in this titration?

[1]
d.

The student repeats the experiment four times to find the volume of NaOH\text{NaOH}NaOH needed for neutralisation. The table shows her results:

Trial1234
Burette reading after adding sodium hydroxide solution (cm3\text{cm}^3cm3)24.8524.3024.5524.20
Burette reading before adding sodium hydroxide solution (cm3\text{cm}^3cm3)0.500.400.500.30
Volume of sodium hydroxide solution added (cm3\text{cm}^3cm3)24.3523.9024.0523.90

The average (mean) volume of sodium hydroxide solution should be calculated using only concordant results. Concordant results are those volumes that differ from each other by 0.20 cm3 or less.

Calculate the average volume of sodium hydroxide solution added.

[2]
e.

In a different experiment under identical conditions, the student records the following titration results with another sample of oxalic acid:

  • Volume of oxalic acid solution added to conical flask: 25.0 cm3
  • Concentration of sodium hydroxide solution: 0.120 mol/dm3
  • Average volume of sodium hydroxide solution added from burette: 22.50 cm3

The equation for the reaction is:

2NaOH+H2C2O4→Na2C2O4+2H2O 2\text{NaOH} + \text{H}_2\text{C}_2\text{O}_4 \rightarrow \text{Na}_2\text{C}_2\text{O}_4 + 2\text{H}_2\text{O} 2NaOH+H2​C2​O4​→Na2​C2​O4​+2H2​O

Calculate the amount, in moles, of NaOH\text{NaOH}NaOH in 22.50 cm3 of the sodium hydroxide solution.

[1]
f.

Calculate the amount, in moles, of H2C2O4\text{H}_2\text{C}_2\text{O}_4H2​C2​O4​ in the oxalic acid solution.

[1]
g.

Calculate the concentration, in mol/dm3\text{mol/dm}^3mol/dm3, of the oxalic acid.

[1]

Acids, alkalis and titrations Questions

  1. IGCSE
  2. /Chemistry
  3. /Acids, alkalis and titrations