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Metallic bonding

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Question 7

Molybdenum (Mo\text{Mo}Mo) is a transition metal. It is extracted from its ore, often starting with molybdenum disulfide (MoS2\text{MoS}_2MoS2​).

a.

Molybdenum disulfide is converted into molybdenum trioxide by heating in air according to the following equation:

2MoS2+7O2→2MoO3+4SO2 2\text{MoS}_2 + 7\text{O}_2 \rightarrow 2\text{MoO}_3 + 4\text{SO}_2 2MoS2​+7O2​→2MoO3​+4SO2​

Why is molybdenum said to be oxidised in this reaction?

[1]
b.

The sulfur dioxide (SO2\text{SO}_2SO2​) formed can be further oxidised in the atmosphere to sulfur trioxide (SO3\text{SO}_3SO3​). This sulfur trioxide then reacts with rainwater to form sulfuric acid (H2SO4\text{H}_2\text{SO}_4H2​SO4​), which contributes to acid rain. Write a balanced chemical equation for the reaction between sulfur trioxide and water.

[1]
c.

The table below shows the melting points of molybdenum trioxide and sulfur trioxide:

CompoundMelting point (∘C^{\circ}\text{C}∘C)
Molybdenum trioxide795795795
Sulfur trioxide171717

What is the type of bonding in a molecule of sulfur trioxide?

[1]
d.

Explain, in terms of structure and bonding, why the melting point of sulfur trioxide is relatively low.

[2]
e.

While molybdenum trioxide has a giant structure, under certain conditions it can form gaseous molecular trimers. Deduce the molecular formula of the molybdenum oxide trimer shown in the diagram below:

Molybdenum oxide trimer molecular structure

[1]
f.

The metallic structure of molybdenum gives it typical metallic properties. Describe the structure and bonding in metallic molybdenum.

[2]
g.

Explain why molybdenum is a good conductor of electricity.

[2]
h.

Explain why molybdenum is malleable.

[2]

Metallic bonding Questions

  1. IGCSE
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  3. /Metallic bonding