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Metallic bonding

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Question 1

Tungsten (W\text{W}W) is a transition metal. It is extracted from its ore, often starting with tungsten disulfide (WS2\text{WS}_2WS2​).

a.

Tungsten disulfide is converted into tungsten trioxide by heating in air according to the following equation:

2WS2+7O2→2WO3+4SO2 2\text{WS}_2 + 7\text{O}_2 \rightarrow 2\text{WO}_3 + 4\text{SO}_2 2WS2​+7O2​→2WO3​+4SO2​

Why is tungsten said to be oxidised in this reaction?

[1]
b.

The sulfur dioxide (SO2\text{SO}_2SO2​) formed in this reaction can react with water in the atmosphere to form sulfurous acid (H2SO3\text{H}_2\text{SO}_3H2​SO3​), which contributes to acid rain. Write a balanced chemical equation for this reaction.

[1]
c.

The table below shows the melting points of tungsten trioxide and sulfur dioxide:

CompoundMelting point (∘C^{\circ}\text{C}∘C)
Tungsten trioxide147314731473
Sulfur dioxide−75-75−75

What is the type of bonding in a molecule of sulfur dioxide?

[1]
d.

Explain, in terms of structure and bonding, why the melting point of sulfur dioxide is very low.

[2]
e.

While tungsten trioxide has a giant structure, under certain conditions it can form gaseous molecular dimers. Deduce the molecular formula of the tungsten oxide dimer shown in the diagram below:

A molecular structure diagram representing a tungsten oxide dimer. It consists of two tungsten atoms, each labeled 'W', and six oxygen atoms, each labeled 'O'. The two W atoms are bridged together by two single-bonded O atoms, forming a central W-O-W-O four-membered ring. In addition, each W atom is double-bonded to two terminal O atoms, pointing outwards.

[1]
f.

The metallic structure of tungsten gives it typical metallic properties.

Describe the structure and bonding in metallic tungsten.

[2]
g.

Explain why tungsten is a good conductor of electricity.

[2]
h.

Explain why tungsten is malleable.

[2]

Metallic bonding Questions

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