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Metallic bonding

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Question 14

Gadolinium is a metal used in medical applications, such as magnetic resonance imaging (MRI) contrast agents.

a.

One stage in the extraction of gadolinium from its ore is to heat gadolinium fluoride with calcium.

The table shows the melting points of the substances involved in this extraction step.

SubstanceMelting point in ∘C^{\circ}\text{C}∘C
calcium842
calcium fluoride1418
gadolinium1313
gadolinium fluoride1400

Balance the equation for this reaction.

‾GdF3+‾Ca→‾Gd+‾CaF2 \text{\underline{\quad\quad}} \text{GdF}_3 + \text{\underline{\quad\quad}} \text{Ca} \rightarrow \text{\underline{\quad\quad}} \text{Gd} + \text{\underline{\quad\quad}} \text{CaF}_2 ​GdF3​+​Ca→​Gd+​CaF2​
[1]
b.

At one point in this extraction, the temperature of the reaction mixture is 1350 ∘C1350\,^{\circ}\text{C}1350∘C.

Which two substances are solids at this temperature?

[1]
c.

Suggest the most likely type of bonding present in gadolinium fluoride.

[1]
d.

Gadolinium reacts with oxygen to form gadolinium oxide. Suggest the chemical formula of gadolinium oxide.

[1]
e.

The diagram shows the particles in gadolinium.

A diagram showing the metallic lattice structure of gadolinium. It contains a regular arrangement of 4 rows of 8 large white circles, closely packed, representing gadolinium ions. Distributed in the interstitial spaces between these circles are small black dots representing electrons. A key on the right shows a large circle representing a gadolinium ion, and a small black dot representing an electron.

Explain, with reference to the diagram, why gadolinium is malleable and a good conductor of electricity.

[2]

Metallic bonding Questions

  1. IGCSE
  2. /Chemistry
  3. /Metallic bonding