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Rates of reaction

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Question 37

An aqueous reaction between sodium thiosulfate (solution A) and dilute hydrochloric acid (solution B) produces a cloudy suspension of yellow sulfur.

To investigate how different factors affect the kinetics of this reaction, a student placed a conical flask containing the reaction mixture on top of a sheet of paper marked with a bold black cross 'X'. The student measured the time taken for the sulfur precipitate to completely obscure the cross when viewed from directly above.

Disappearing cross experiment

The student's results are recorded in the table below:

TrialConcentration of sodium thiosulfate in mol/dm3\text{mol/dm}^3mol/dm3Temperature in ∘C^{\circ}\text{C}∘CTime taken for cross to disappear in s\text{s}s
10.0520180
20.054045
30.204011

Use the results in the table to explain, in terms of collision theory, the effect of:

  1. changing the temperature, and
  2. changing the concentration of sodium thiosulfate, on the rate of this reaction.
[6]

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