Titanium is an extremely useful metal due to its low density, high strength, and resistance to corrosion. However, its industrial extraction is highly expensive.
Which statement correctly explains why titanium cannot be extracted from titanium(IV) oxide by direct reduction with carbon, and identifies the correct method used instead?
Direct reduction with carbon is thermodynamically impossible at all temperatures; instead, titanium(IV) oxide is reduced directly using hydrogen gas (H2H_2H2) at high temperatures.
Direct reduction with carbon produces titanium carbide (TiCTiCTiC), which makes the metal extremely brittle; instead, titanium(IV) oxide is converted to titanium(IV) chloride (TiCl4TiCl_4TiCl4) and reduced with magnesium or sodium.
Direct reduction with carbon is highly exothermic and leads to uncontrollable thermal runaway; instead, titanium(IV) oxide is dissolved in molten cryolite (Na3AlF6Na_3AlF_6Na3AlF6) and extracted via electrolysis.
Direct reduction with carbon is too slow to be industrially viable; instead, titanium(IV) oxide is reacted with scrap iron (FeFeFe) in a displacement reaction to yield pure titanium.
110 exam-style questions on Edexcel GCSE Chemistry 5.1 Obtaining and using metals, covering 5.1.1 The reactivity series of metals, 5.1.2 Displacement reactions as redox reactions, 5.1.3 Extracting metals from ores by reduction, 5.1.4 Biological methods of metal extraction, 5.1.5 Resistance to oxidation and recycling metals, and 5.1.6 Life cycle assessment. Each one has a worked solution and a mark scheme showing where the marks go.