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Question 18

Chlorine, Cl2\text{Cl}_2Cl2​, reacts with nitrogen dioxide, NO2\text{NO}_2NO2​, to form nitryl chloride, NO2Cl\text{NO}_2\text{Cl}NO2​Cl, as shown reactively below:

Cl2+2NO2→2NO2Cl \text{Cl}_2 + 2\text{NO}_2 \rightarrow 2\text{NO}_2\text{Cl} Cl2​+2NO2​→2NO2​Cl

The mechanism for this reaction involves two steps. Step 1 is the 'slow' step and Step 2 is the 'fast' step.

The equation for Step 2 is shown below:

Cl+NO2→NO2Cl \text{Cl} + \text{NO}_2 \rightarrow \text{NO}_2\text{Cl} Cl+NO2​→NO2​Cl

Suggest the equation for Step 1 and the rate equation for this overall reaction.

[2]

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