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Energetics

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Question 1

An environmental scientist investigates the energetics of dissolving anhydrous calcium chloride in water to design a portable self-heating pack.

The scientist uses 150.0 g150.0\text{ g}150.0 g of water in a polystyrene cup. The temperature of the water is recorded before and after adding the anhydrous calcium chloride:

  • Temperature of water before adding calcium chloride: 19.5∘C19.5^\circ\text{C}19.5∘C
  • Temperature of water after adding calcium chloride: 26.7∘C26.7^\circ\text{C}26.7∘C
a.

Calculate the temperature change of the mixture in ∘C^\circ\text{C}∘C.

[1]
b.

Calculate the heat energy change, in joules, using the expression:

heat energy change (J)=mass of water (g)×4.18×temperature change (∘C) \text{heat energy change (J)} = \text{mass of water (g)} \times 4.18 \times \text{temperature change (}^\circ\text{C)} heat energy change (J)=mass of water (g)×4.18×temperature change (∘C)
[1]
c.

The scientist used 6.66 g6.66\text{ g}6.66 g of anhydrous calcium chloride. Calculate the amount, in moles, of calcium chloride dissolved (Mr of CaCl2=111M_r\text{ of CaCl}_2 = 111Mr​ of CaCl2​=111).

[1]
d.

Calculate the molar enthalpy change, in kJ/mol\text{kJ/mol}kJ/mol, for dissolving anhydrous calcium chloride. Since the temperature increased, include the appropriate sign (+++ or −-−) with your value.

[2]

Energetics Questions

  1. IGCSE
  2. /Chemistry
  3. /Energetics