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5.2 Reversible reactions and equilibria

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Question 1
H

In the Haber process, nitrogen and hydrogen react to form ammonia.

N2(g)+3H2(g)⇌2NH3(g)\mathrm{N_{2}(g)} + \mathrm{3H_{2}(g)} \rightleftharpoons \mathrm{2NH_{3}(g)}N2​(g)+3H2​(g)⇌2NH3​(g)

The table shows the percentage of ammonia in the equilibrium mixture at 200 atm and different temperatures.

Temperature / °CPercentage of ammonia at equilibrium (%)
30063
35050
40039
45028
50018
a.

Use the table to deduce whether the forward reaction is exothermic or endothermic. Explain your answer.

[2]
b.

The industrial conditions are a temperature of 450 °C, a pressure of 200 atm and an iron catalyst. Explain why these conditions are used. You should refer to rate, yield and cost in your answer.

[6]
c.

A plant uses 5.6 tonnes of nitrogen. Calculate the maximum mass of ammonia, in tonnes, that could be made. Relative formula masses: N2=28,NH3=17\mathrm{N_{2}} = 28, \mathrm{NH_{3}} = 17N2​=28,NH3​=17

[3]
d.

After recycling the unreacted gases, the plant obtains 6.12 tonnes of ammonia from the 5.6 tonnes of nitrogen. Calculate the percentage yield.

[2]
Markscheme

5.2 Reversible reactions and equilibria Questions

  1. GCSE
  2. /Chemistry
  3. /5.2 Reversible reactions and equilibria

45 exam-style questions on Edexcel GCSE Chemistry 5.2 Reversible reactions and equilibria, covering 5.2.1 Reversible reactions and dynamic equilibrium, 5.2.2 The Haber process, and 5.2.3 Changing the position of a dynamic equilibrium. Each one has a worked solution and a mark scheme showing where the marks go.

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