Use of amount of substance in relation to masses of pure substances

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Question 2
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Titanium is extracted from titanium dioxide using the Hunter process in a two-stage industrial method.

Stage 1 $\quad

\text{TiO}_2 + 2\text{C} + 2\text{Cl}_2 \rightarrow \text{TiCl}_4 + 2\text{CO}$ **Stage 2** $\quad

\text{TiCl}_4 + 4\text{Na} \rightarrow \text{Ti} + 4\text{NaCl}$

a.

Suggest one hazard associated with Stage 1.

[1]
b.

Suggest why the reaction in Stage 2 is carried out in an atmosphere of argon and not in air.

[2]
c.

Titanium chloride (TiCl4\text{TiCl}_4TiCl4​) is a liquid at room temperature. Explain why you would not expect a transition metal chloride to be a liquid at room temperature.

[3]
d.

During Stage 2, sodium atoms are oxidised to sodium ions. Complete the half-equation for this oxidation. Na→Na++‾\text{Na} \rightarrow \text{Na}^{+} + \underline{\qquad\qquad}Na→Na++​

[1]
e.

In Stage 2, 47.5 kg47.5\text{ kg}47.5 kg of titanium chloride was added to 25.0 kg25.0\text{ kg}25.0 kg of sodium. Relative atomic masses (ArA_rAr​): Na=23\text{Na} = 23Na=23, Cl=35.5\text{Cl} = 35.5Cl=35.5, Ti=48\text{Ti} = 48Ti=48 Explain why titanium chloride is the limiting reactant. You must show your working.

[4]
f.

For a Stage 2 reaction, the percentage yield of titanium was 84.5%84.5\%84.5%. The theoretical maximum mass of titanium produced in this batch was 18.5 kg18.5\text{ kg}18.5 kg. Calculate the actual mass of titanium produced. Give your answer to 3 significant figures.

[2]

Use of amount of substance in relation to masses of pure substances Questions

  1. GCSE
  2. /Chemistry
  3. /Use of amount of substance in relation to masses of pure substances