Transition metals (A-level only)

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Question 3
Medium

Which statement about transition metals and their complexes is not correct?

The reaction of [Cu(H2O)6]2+[\text{Cu}(\text{H}_2\text{O})_6]^{2+}[Cu(H2​O)6​]2+ with excess concentrated HCl\text{HCl}HCl results in a change in coordination number from 6 to 4 because chloride ligands are larger than water molecules.

The substitution of monodentate ligands by multidentate ligands like EDTA4−\text{EDTA}^{4-}EDTA4− is thermodynamically highly favourable because the reaction is strongly exothermic (ΔH⊖≪0\Delta H^{\ominus} \ll 0ΔH⊖≪0).

Zinc is not classified as a transition metal because neither the metal nor its common stable ion (Zn2+\text{Zn}^{2+}Zn2+) has an incomplete d-subshell.

The splitting of the d-orbitals in transition metal complexes depends on the oxidation state of the metal, the identity of the metal, and the nature of the ligands.

Transition metals (A-level only) Questions

  1. A Level
  2. /Chemistry
  3. /Transition metals (A-level only)