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Transition metals (A-level only)

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Question 26

This question is about complexes of the transition metal iron.

1.

State the meaning of the term transition metal complex.

[1]
2.

Fe(PCl3)5Fe(PCl_3)_5Fe(PCl3​)5​ is a complex of iron that contains molecules of PCl3PCl_3PCl3​. The electron pair repulsion theory can be used to predict the shape of a PCl3PCl_3PCl3​ molecule. Draw the shape of a PCl3PCl_3PCl3​ molecule. Include any lone pairs of electrons that influence the shape. Name the shape.

[2]
3.

Suggest why the oxidation state of iron is zero in Fe(PCl3)5Fe(PCl_3)_5Fe(PCl3​)5​.

[1]
4.

The compound [Fe(NH3)4Cl2]Cl[Fe(NH_3)_4Cl_2]Cl[Fe(NH3​)4​Cl2​]Cl contains ammonia molecules. Deduce the oxidation state of iron in [Fe(NH3)4Cl2]Cl[Fe(NH_3)_4Cl_2]Cl[Fe(NH3​)4​Cl2​]Cl.

[1]
5.

Name the type of bond between N and H in ammonia.

[1]
6.

The compound [Fe(NH3)4Cl2]Cl[Fe(NH_3)_4Cl_2]Cl[Fe(NH3​)4​Cl2​]Cl contains a complex ion that shows isomerism. Draw the two isomers of the complex ion. State the type of isomerism shown.

[2]
7.

Complete the equation to show the formation of one complex that contains iron in its +3 oxidation state:

FeCl3+5H2O→ FeCl_3 + 5H_2O \rightarrow FeCl3​+5H2​O→
[1]
Markscheme

Transition metals (A-level only) Questions

  1. A Level
  2. /Chemistry
  3. /Transition metals (A-level only)

63 exam-style questions on AQA A Level Chemistry Transition metals (A-level only), covering General properties of transition metals (A-level only), Substitution reactions (A-level only), Shapes of complex ions (A-level only), Formation of coloured ions (A-level only), Variable oxidation states (A-level only), and Catalysts (A-level only). Each one has a worked solution and a mark scheme showing where the marks go.

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