Energetics

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Question 13
Medium

A student carries out an experiment to determine the enthalpy of combustion of liquid propan-1-ol (C3H7OH\text{C}_3\text{H}_7\text{OH}C3​H7​OH).

They use a spirit burner containing propan-1-ol, positioned below a clamped aluminium calorimeter containing 120 g120\text{ g}120 g of water.

Answer the following questions based on this experiment:

1.

Construct a table to record all the raw experimental measurements required to calculate the experimental enthalpy of combustion of propan-1-ol in this investigation. Ensure you include appropriate units.

[2]
2.

Another student suggests replacing the clamped aluminium calorimeter with a thick-walled ceramic crucible supported by a clay pipe triangle on a tripod. Suggest two distinct disadvantages of this proposed modification.

[3]
3.

Explain two reasons why the calculated value for the enthalpy of combustion of propan-1-ol from this calorimetry experiment is significantly less exothermic than the accepted literature value.

[3]
4.

Identify one practical improvement, other than changing the material or vessel type of the calorimeter, that would increase the accuracy of the calculated enthalpy value.

[1]

Energetics Questions

  1. A Level
  2. /Chemistry
  3. /Energetics