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Electrolysis

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Question 3

Magnesium and its compounds have many important industrial uses.

Magnesium is an abundant metal found in minerals such as magnesite, rather than as a pure native element in the Earth's crust.

a.

Suggest why magnesium is never found as a pure element in the Earth's crust.

[1]
b.

Magnesium can be processed and extracted using a multi-stage process:

  • Stage 1: Magnesium carbonate is heated to form magnesium oxide and another product.
  • Stage 2: The magnesium oxide is reacted with dilute hydrochloric acid to form magnesium chloride solution.
  • Stage 3: The magnesium chloride solution is evaporated to obtain solid magnesium chloride.
  • Stage 4: The solid magnesium chloride is melted and electrolysed.

Which stage involves a neutralisation reaction?

  • A Stage 1
  • B Stage 2
  • C Stage 3
  • D Stage 4
[1]
c.

Suggest the name of the other product formed in Stage 1.

[1]
d.

What happens to the ions in magnesium chloride during melting?

[1]
e.

The ionic half-equation for the reaction at the negative electrode in Stage 4 is:

Mg2++2e−→Mg \text{Mg}^{2+} + 2\text{e}^- \rightarrow \text{Mg} Mg2++2e−→Mg

Write the ionic half-equation for the reaction at the positive electrode.

[1]
f.

A manufacturer makes a batch of magnesium by electrolysing molten magnesium chloride. Use Ar(Mg)=24A_r(\text{Mg}) = 24Ar​(Mg)=24 and Ar(Cl)=35.5A_r(\text{Cl}) = 35.5Ar​(Cl)=35.5.

Calculate the mass of magnesium chloride (MgCl2\text{MgCl}_2MgCl2​) needed to make 120 kg120\text{ kg}120 kg of magnesium.

[2]
g.

Calculate the amount, in moles, of electrons needed to make 120 kg120\text{ kg}120 kg of magnesium.

[2]
h.

Magnesium oxide can be used to make magnesium sulfate by this reaction:

MgO(s)+H2SO4(aq)→MgSO4(aq)+H2O(l) \text{MgO(s)} + \text{H}_2\text{SO}_4\text{(aq)} \rightarrow \text{MgSO}_4\text{(aq)} + \text{H}_2\text{O(l)} MgO(s)+H2​SO4​(aq)→MgSO4​(aq)+H2​O(l)

A student is provided with a beaker of dilute sulfuric acid. Outline the steps she should use to obtain a pure sample of hydrated magnesium sulfate crystals using this reaction.

[5]

Electrolysis Questions

  1. IGCSE
  2. /Chemistry
  3. /Electrolysis