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Electrolysis

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Question 12

This question is about the extraction and uses of magnesium.

a.

Magnesium is extracted from molten magnesium chloride MgCl2\text{MgCl}_2MgCl2​ by electrolysis. The positive electrode (anode) is made of graphite, and the negative electrode (cathode) is made of steel.

State why graphite is suitable for use as the positive electrode.

[1]
b.

State why steel is suitable for use as the negative electrode.

[1]
c.

Explain why the operating temperature would need to be very high (over 700∘C700^\circ\text{C}700∘C) if pure magnesium chloride were used as the electrolyte.

[2]
d.

Describe how the operating temperature of the electrolysis cell is kept lower.

[1]
e.

The ionic half-equation for the reaction at the negative electrode is:

Mg2++2e−→Mg \text{Mg}^{2+} + 2\text{e}^- \rightarrow \text{Mg} Mg2++2e−→Mg

What type of reaction is occurring at the negative electrode? Explain your answer.

[2]
f.

Chlorine gas is produced at the positive electrode during this electrolysis. Describe how chlorine gas is formed from chloride ions.

[2]
g.

Magnesium is alloyed with other metals to make lightweight components for aircraft and spacecraft.

State two properties of magnesium alloys that make them suitable for this use. You should not refer to cost in your answers.

[2]

Electrolysis Questions

  1. IGCSE
  2. /Chemistry
  3. /Electrolysis