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Electrolysis

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Question 14

This question is about the extraction and uses of calcium.

a.

Calcium is extracted from molten calcium chloride CaCl2\text{CaCl}_2CaCl2​ by electrolysis. The positive electrode (anode) is made of graphite, and the negative electrode (cathode) is made of steel.

State why graphite is suitable for use as the positive electrode.

[1]
b.

State why steel is suitable for use as the negative electrode.

[1]
c.

Explain why the operating temperature would need to be very high (over 770∘C770^\circ\text{C}770∘C) if pure calcium chloride were used as the electrolyte.

[2]
d.

Describe how the operating temperature of the electrolysis cell is kept lower.

[1]
e.

The ionic half-equation for the reaction at the negative electrode is:

Ca2++2e−→Ca \text{Ca}^{2+} + 2\text{e}^- \rightarrow \text{Ca} Ca2++2e−→Ca

What type of reaction is occurring at the negative electrode? Explain your answer.

[2]
f.

Chlorine gas is produced at the positive electrode during this electrolysis. Describe how chlorine gas is formed from chloride ions.

[2]
g.

Calcium is alloyed with other metals to make durable components such as maintenance-free lead-acid automotive batteries or structural components.

State two properties of calcium alloys that make them suitable for these uses. You should not refer to cost in your answers.

[2]

Electrolysis Questions

  1. IGCSE
  2. /Chemistry
  3. /Electrolysis