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3.3 Yield and atom economy of chemical reactions

3.3 Yield and atom economy of chemical reactions

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Question 4

Lead(II) iodide is a bright yellow pigment historically used in art. It is produced by the precipitation reaction between lead(II) nitrate solution and potassium iodide solution:

Pb(NO3)2(aq)+2KI(aq)→PbI2(s)+2KNO3(aq) \text{Pb(NO}_3)_2\text{(aq)} + 2\text{KI(aq)} \rightarrow \text{PbI}_2\text{(s)} + 2\text{KNO}_3\text{(aq)} Pb(NO3​)2​(aq)+2KI(aq)→PbI2​(s)+2KNO3​(aq)

A student investigated the law of conservation of mass using the following method:

  1. Pour lead(II) nitrate solution into beaker A.
  2. Pour potassium iodide solution into beaker B.
  3. Measure the masses of both beakers and their contents.
  4. Pour the solution from beaker B into beaker A.
  5. Measure the masses of both beakers and their contents again.

The table below shows the student's results:

Mass before mixing (g)Mass after mixing (g)
Beaker A and contents92.45135.31
Beaker B and contents78.1235.26
a.

Explain how the results demonstrate the law of conservation of mass. You must use data from the table in your answer.

[3]
b.

Calculate the percentage atom economy for the production of lead(II) iodide (PbI2\text{PbI}_2PbI2​) in this reaction. Give your answer to 3 significant figures.

Relative formula masses (MrM_{\text{r}}Mr​): Pb(NO3)2=331\text{Pb(NO}_3)_2 = 331Pb(NO3​)2​=331, KI=166\text{KI} = 166KI=166, PbI2=461\text{PbI}_2 = 461PbI2​=461, KNO3=101\text{KNO}_3 = 101KNO3​=101

[4]
Markscheme

3.3 Yield and atom economy of chemical reactions Questions

  1. GCSE
  2. /Chemistry
  3. /3.3 Yield and atom economy of chemical reactions

31 exam-style questions on AQA GCSE Chemistry 3.3 Yield and atom economy of chemical reactions, covering 3.3.1 Percentage yield and 3.3.2 Atom economy. Each one has a worked solution and a mark scheme showing where the marks go.

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