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Rates of reaction

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Question 21

An experiment is conducted to study the rate of reaction between calcium carbonate and dilute hydrochloric acid. Carbon dioxide gas is collected using a gas syringe.

a.

Write a balanced chemical equation for the reaction between calcium carbonate and hydrochloric acid. Include state symbols.

[2]
b.

Describe a chemical test to show that the gas collected in the syringe is carbon dioxide.

[2]
c.

State and explain the effect of increasing the temperature on the rate of this reaction, in terms of collision theory.

[3]
d.

The graph below shows the results from an experiment using excess calcium carbonate and 50 cm350\text{ cm}^350 cm3 of 1.0 mol/dm31.0\text{ mol/dm}^31.0 mol/dm3 hydrochloric acid at 20 ∘C20\ ^\circ\text{C}20 ∘C.

A graph plotting Cumulative Volume of Carbon Dioxide in cubic centimeters on the vertical y-axis against Time in seconds on the horizontal x-axis. The y-axis ranges from 0 to 100 with divisions of 10. The x-axis ranges from 0 to 120 with divisions of 10. The curve starts at (0, 0), passes through (10, 24), (20, 42), (30, 56), (40, 66), (50, 74), (60, 78), and levels off horizontally at exactly 80 cm³ at 80 seconds, continuing flat at 80 cm³ up to 120 seconds.

On the same axes, sketch the curve you would expect with excess calcium carbonate and 50 cm350\text{ cm}^350 cm3 of 0.5 mol/dm30.5\text{ mol/dm}^30.5 mol/dm3 hydrochloric acid at 20 ∘C20\ ^\circ\text{C}20 ∘C. Label this curve A.

[2]
e.

On the same axes, sketch the curve you would expect with excess calcium carbonate and 50 cm350\text{ cm}^350 cm3 of 1.0 mol/dm31.0\text{ mol/dm}^31.0 mol/dm3 hydrochloric acid at 35 ∘C35\ ^\circ\text{C}35 ∘C. Label this curve B.

[2]

Rates of reaction Questions

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