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Group 1 (alkali metals) – lithium, sodium and potassium

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Question 18

The table gives information about the first four elements in Group 1 of the Periodic Table.

ElementAtomic numberElectronic configurationMelting point (°C\degree\text{C}°C)Reaction with water
lithium32.1180fizzes, floats and moves slowly on the surface
sodium112.8.198melts into a ball, fizzes rapidly and moves quickly
potassium192.8.8.163burns with a lilac flame, reacts very vigorously
rubidium372.8.18.8.139reacts explosively
a.

Francium (Fr\text{Fr}Fr) has an atomic number of 87 and is the seventh element in Group 1.

It is possible to make predictions about francium by comparison with the other elements in Group 1.

How many electrons does an atom of francium have in its outer shell?

[1]
b.

What physical state at 15°C15\degree\text{C}15°C and approximate melting point (higher or lower than 28°C28\degree\text{C}28°C) would you expect for francium?

  • Physical state:
  • Melting point:
[1]
c.

Predict the formula of the compound formed between francium and chlorine. Suggest a name for this compound.

  • Formula:
  • Name:
[1]
d.

Suggest how the reactivity of francium with water compares to that of rubidium. Explain your answer.

[2]
e.

Hydrogen gas can be prepared in the laboratory by reacting zinc metal with dilute hydrochloric acid.

Balance the equation for the reaction:

…Zn(s)+…HCl(aq)→…ZnCl2(aq)+…H2(g) \dots\text{Zn}(\text{s}) + \dots\text{HCl}(\text{aq}) \rightarrow \dots\text{ZnCl}_2(\text{aq}) + \dots\text{H}_2(\text{g}) …Zn(s)+…HCl(aq)→…ZnCl2​(aq)+…H2​(g)
[1]
f.

State what you would observe when a lighted splint is held to the mouth of a test tube containing hydrogen gas.

[1]
g.

Lithium can be extracted from mineral brines containing lithium ions, Li+\text{Li}^+Li+.

The stages in the extraction of lithium from brine are:

  • Stage 1: Sodium carbonate is added to the brine to precipitate lithium carbonate, Li2CO3\text{Li}_2\text{CO}_3Li2​CO3​.
  • Stage 2: The lithium carbonate is filtered off and reacted with hydrochloric acid to form aqueous lithium chloride, LiCl\text{LiCl}LiCl.
  • Stage 3: The lithium chloride solution is evaporated to obtain solid lithium chloride.
  • Stage 4: Molten lithium chloride is electrolysed to produce lithium metal and chlorine gas.

Suggest a substance (other than sodium carbonate) that could be added to brine in Stage 1 to provide carbonate ions.

[1]
h.

Why is an excess of hydrochloric acid added in Stage 2?

[1]
i.

Write a chemical equation for the reaction in Stage 2.

[1]
j.

Write a chemical equation for the reaction in Stage 4.

[1]
k.

State the colour change observed when bromine water is added to an aqueous solution of sodium iodide.

  • Colour of sodium iodide solution at start:
  • Colour of final reaction mixture:
[2]

Group 1 (alkali metals) – lithium, sodium and potassium Questions

  1. IGCSE
  2. /Chemistry
  3. /Group 1 (alkali metals) – lithium, sodium and potassium