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Question 19

The ions present in ionic compounds can be identified using simple tests.

  • Some cations (positive ions) can be identified using a flame test.
  • Some anions (negative ions) can be identified by observing reactions in solutions of the compounds.

Table 1 shows the flame test colours for four cations.

Table 1

CationFlame test colour
caesiumblue
rubidiumviolet
strontiumred
tantalumblue

Table 2 shows the results of three tests used to identify anions in solution.

Table 2

AnionHydrochloric acid addedMagnesium chloride solution addedMethyl orange added
carbonateeffervescencewhite precipitate formsyellow
chlorideno changeno changeorange
hydrogencarbonateeffervescenceno changeyellow
hydrogensulfateno changeno changered
hydroxideno changewhite precipitate formsyellow

Use the information in the tables to answer these questions.

a.

In the tests, compound A gives a violet flame and produces no change when magnesium chloride solution is added.

Suggest two possible identities for compound A.

[2]
b.

In the tests, compound B gives a blue flame and produces a white precipitate when magnesium chloride solution is added.

A student concludes that compound B is caesium carbonate.

Give two reasons why this conclusion may not be correct.

[2]
c.

Which additional test from Table 2 would show whether the anion in compound B is carbonate or hydroxide?

[1]
d.

An aqueous solution contains either chloride ions or hydrogensulfate ions.

Using only information from the tables, explain how you could decide if the solution contains chloride or hydrogensulfate ions.

[2]

Chemical tests Questions

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