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Question 16

Part (a)

The table shows information about the effect of adding sodium hydroxide solution to solutions containing magnesium ions, calcium ions or aluminium ions.

Ion in solutionEffect of adding a few drops of sodium hydroxide solutionEffect of adding excess sodium hydroxide solution
magnesium, Mg2+\text{Mg}^{2+}Mg2+white precipitate formswhite precipitate remains
calcium, Ca2+\text{Ca}^{2+}Ca2+white precipitate formswhite precipitate remains
aluminium, Al3+\text{Al}^{3+}Al3+white precipitate formswhite precipitate disappears
a.

A student is provided with a sample of a white solid. The student dissolves some of the white solid in water and then adds a few drops of sodium hydroxide solution. A white precipitate forms. She concludes that the sample contains calcium ions. Explain whether the student’s conclusion is valid.

[2]
b.

Give a different test to show that the white solid contains calcium ions. Identify the test and the expected result.

[2]
c.

Part (b)

A hydrated salt has the formula AB2⋅xH2O\text{AB}_2 \cdot x\text{H}_2\text{O}AB2​⋅xH2​O where A\text{A}A is a positive metal ion and B\text{B}B is a negative ion. When the hydrated salt is heated, this reaction occurs:

AB2⋅xH2O→AB2+xH2O \text{AB}_2 \cdot x\text{H}_2\text{O} \rightarrow \text{AB}_2 + x\text{H}_2\text{O} AB2​⋅xH2​O→AB2​+xH2​O

A scientist heats a sample of the hydrated salt until all the water has been lost. She records the mass of the salt before and after heating. The table shows her results.

Mass of hydrated saltMass of salt after heating
2.94 g2.22 g

Describe how the scientist could make sure that all the water has been lost.

[2]
d.

Use the scientist’s results to find the value of x x\,x in AB2⋅xH2O\text{AB}_2 \cdot x\text{H}_2\text{O}AB2​⋅xH2​O. [Mr of AB2=111,Mr of H2O=18][M_{\text{r}} \text{ of } \text{AB}_2 = 111, \quad M_{\text{r}} \text{ of } \text{H}_2\text{O} = 18][Mr​ of AB2​=111,Mr​ of H2​O=18]

[4]
e.

Part (c)

Describe how the scientist could use a solution of the salt to find out if the negative ions are chloride ions.

[3]
f.

Part (d)

The test shows that the negative ions are chloride ions. Calculate the relative atomic mass of metal A\text{A}A using the formula and MrM_{\text{r}}Mr​ value of the anhydrous salt, AB2\text{AB}_2AB2​.

[1]
g.

Identify metal A\text{A}A.

[1]
Markscheme

Chemical tests Questions

  1. IGCSE
  2. /Chemistry
  3. /Chemical tests

35 exam-style questions on Edexcel IGCSE Chemistry Chemical tests. Each one has a worked solution and a mark scheme showing where the marks go.

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