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Acids, bases and salt preparations

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Question 3

A student tries to make a pure, dry sample of hydrated copper(II) sulfate crystals. She uses dilute sulfuric acid and solid copper(II) oxide. This is the student's method:

  • Step 1: pour about 50 cm3 of dilute sulfuric acid into a beaker
  • Step 2: warm the acid using a Bunsen burner
  • Step 3: add a small amount of copper(II) oxide and stir the mixture with a glass rod
  • Step 4: add further small amounts of copper(II) oxide until it stops reacting
  • Step 5: filter the final mixture and collect the filtrate in an evaporating basin
  • Step 6: leave the filtrate until all of the water has evaporated

Her sample of copper(II) oxide contains a small amount of solid impurity that dissolves in water, but does not react with the acid.

a.

State why it is not necessary to have a precise measurement of the volume of sulfuric acid in step 1.

[1]
b.

State why the acid is warmed in step 2.

[1]
c.

Suggest why a glass rod, rather than a metal spatula, is used to stir the mixture in step 3.

[1]
d.

State how the student will know when the copper(II) oxide stops reacting in step 4.

[1]
e.

State why the method used in step 6 will not produce a pure sample of hydrated copper(II) sulfate crystals.

[1]
f.

Describe how the student could produce a pure, dry sample of crystals from the filtrate in step 5.

[5]
g.

The table below shows the formula and colour of three different types of copper(II) sulfate.

FormulaColour
CuSO4\text{CuSO}_4CuSO4​white
CuSO4⋅H2O\text{CuSO}_4\cdot\text{H}_2\text{O}CuSO4​⋅H2​Opale blue
CuSO4⋅5H2O\text{CuSO}_4\cdot5\text{H}_2\text{O}CuSO4​⋅5H2​Oblue

When water is added very slowly to solid CuSO4\text{CuSO}_4CuSO4​, the colour changes from white to pale blue and then to blue.

Write a chemical equation for the change from the pale blue solid to the blue solid.

[1]
h.

Which of these words describes the change taking place when the blue solid is heated to form the white solid?

  • A: crystallisation
  • B: dehydration
  • C: hydration
  • D: redox
[1]

Acids, bases and salt preparations Questions

  1. IGCSE
  2. /Chemistry
  3. /Acids, bases and salt preparations