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Acids, bases and salt preparations

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Question 7

A student tries to make a pure, dry sample of hydrated cobalt(II) chloride crystals. She uses dilute hydrochloric acid and solid cobalt(II) carbonate. This is the student's method:

  • Step 1: pour about 40 cm340\text{ cm}^340 cm3 of dilute hydrochloric acid into a beaker
  • Step 2: warm the acid using a Bunsen burner
  • Step 3: add a small amount of cobalt(II) carbonate and stir the mixture with a glass rod
  • Step 4: add further small amounts of cobalt(II) carbonate until it stops reacting
  • Step 5: filter the final mixture and collect the filtrate in an evaporating basin
  • Step 6: leave the filtrate until all of the water has evaporated

Her sample of cobalt(II) carbonate contains a small amount of solid impurity that dissolves in water, but does not react with the acid.

a.

State why it is not necessary to have a precise measurement of the volume of hydrochloric acid in step 1.

[1]
b.

State why the acid is warmed in step 2.

[1]
c.

Suggest why a glass rod, rather than a metal spatula, is used to stir the mixture in step 3.

[1]
d.

State how the student will know when the cobalt(II) carbonate stops reacting in step 4.

[1]
e.

State why the method used in step 6 will not produce a pure sample of hydrated cobalt(II) chloride crystals.

[1]
f.

Describe how the student could produce a pure, dry sample of crystals from the filtrate in step 5.

[5]
g.

The table below shows the formula and colour of three different types of cobalt(II) chloride.

FormulaColour
CoCl2\text{CoCl}_2CoCl2​blue
CoCl2⋅2H2O\text{CoCl}_2\cdot2\text{H}_2\text{O}CoCl2​⋅2H2​Oviolet
CoCl2⋅6H2O\text{CoCl}_2\cdot6\text{H}_2\text{O}CoCl2​⋅6H2​Opink

When water is added very slowly to solid CoCl2\text{CoCl}_2CoCl2​, the colour changes from blue to violet and then to pink.

Write a chemical equation for the change from the violet solid to the pink solid.

[1]
h.

Which of these words describes the change taking place when the pink solid is heated to form the blue solid?

  • A: condensation
  • B: dehydration
  • C: hydration
  • D: reduction
[1]

Acids, bases and salt preparations Questions

  1. IGCSE
  2. /Chemistry
  3. /Acids, bases and salt preparations