A full outer shell makes the noble gases inert
Noble gas
An element in Group 0 of the periodic table, which has a full outer shell of electrons.
Inert
Describes a substance that does not readily take part in chemical reactions.
- Helium, neon, argon, krypton and xenon all have a full outer shell of electrons.
- A full shell is eight electrons, except for helium, which is full with two.
- Reacting means gaining, losing or sharing electrons to reach a full shell.
- A noble gas already has one, so it has nothing to gain from reacting.
- They are therefore inert, and they exist as single atoms rather than as molecules.
Other elements react so as to reach the full outer shell a noble gas already has.
Uses that depend on being inert
- Argon fills filament light bulbs, where it stops the hot filament burning away.
- Argon also shields the weld in arc welding, keeping air away from the hot metal.
- Helium and argon protect delicate objects in storage from reacting with air.
- An unreactive gas is chosen wherever a reaction with oxygen or nitrogen would cause damage.
- Air would not do the job, because its oxygen reacts with hot or exposed material.
- Filament lamp: argon, because it will not react with the glowing filament.
- Welding: argon, because it keeps oxygen away from the molten metal.
Uses that depend on low density and non-flammability
- Helium has a very low density, so a balloon filled with it rises.
- Helium is also non-flammable, which is why it replaced hydrogen in airships.
- Hydrogen is lighter still, but it burns, which made it dangerous.
- Neon glows red-orange when a current passes through it, which is used in display signs.
- Each use is matched to a property, so the reason for the choice can always be named.
Helium is chosen over hydrogen for safety, not because it is lighter.
The trend in physical properties down the group
- Boiling points rise steadily down the group, from helium at the top.
- Helium boils at about −269 ∘C-269\ ^{\circ}\text{C}−269 ∘C, the lowest of any element.
- Density also rises down the group, so helium is the least dense and radon the most.
- All the noble gases are gases at room temperature, despite the rise in boiling point.
- The rise follows the same reason as in Group 7: larger atoms attract one another more strongly.
These are atoms, not molecules, so the attractions being overcome act between single atoms.
Predicting the properties of other noble gases
- A gas lower in the group has a higher boiling point and a higher density than one above it.
- Krypton therefore has a higher boiling point than argon and a lower one than xenon.
- Radon, at the bottom, has the highest boiling point and the greatest density.
- Every one of them stays inert, because they all have a full outer shell.
- A prediction is made by placing the element in the group and reading the neighbouring values.
- Why are the noble gases chemically inert?
- Why is helium full with only two outer electrons?
- Give a use of argon and the property it depends on.
- Why was helium used in airships instead of hydrogen?
- Predict how the density of krypton compares with that of argon.