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7.2 Group 7

7.2 Group 7

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Question 16

An analytical chemist is tasked with establishing the trend in oxidising ability (relative reactivity) of three halogens: chlorine, bromine, and iodine.

They are provided with:

  • Aqueous solutions of the halogens: chlorine water (Cl2(aq)Cl_2(aq)Cl2​(aq)), bromine water (Br2(aq)Br_2(aq)Br2​(aq)), and iodine solution (I2(aq)I_2(aq)I2​(aq))
  • Aqueous solutions of their sodium salts: sodium chloride (NaCl(aq)NaCl(aq)NaCl(aq)), sodium bromide (NaBr(aq)NaBr(aq)NaBr(aq)), and sodium iodide (NaI(aq)NaI(aq)NaI(aq))
  • An organic solvent: cyclohexane (C6H12C_6H_{12}C6​H12​)

Describe a systematic experimental procedure the chemist should follow to determine the relative oxidising power of these three halogens, incorporating the use of cyclohexane to make the observations clearer.

In your answer, you should:

  • explain how the observations, particularly within the organic layer, allow the determination of the trend
  • write balanced ionic equations for any two of the displacement reactions that occur.
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Markscheme

7.2 Group 7 Questions

  1. GCSE
  2. /Chemistry
  3. /7.2 Group 7

106 exam-style questions on Edexcel GCSE Chemistry 7.2 Group 7, covering 7.2.1 Physical properties of the halogens, 7.2.2 Reactions of the halogens, 7.2.3 Relative reactivity and displacement reactions of the halogens, and 7.2.4 Halogen displacement as a redox reaction. Each one has a worked solution and a mark scheme showing where the marks go.

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