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Rates, equilibrium and pH

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Question 27

Dinitrogen pentoxide (N2O5\text{N}_2\text{O}_5N2​O5​) can be produced by the gas-phase reaction of nitrogen dioxide (NO2\text{NO}_2NO2​) with ozone (O3\text{O}_3O3​) according to the following equation:

2NO2+O3→N2O5+O2 2\text{NO}_2 + \text{O}_3 \rightarrow \text{N}_2\text{O}_5 + \text{O}_2 2NO2​+O3​→N2​O5​+O2​

The proposed mechanism for this reaction occurs in two steps, where Step 1 is the slow, rate-determining step and Step 2 is a fast step.

The equation for Step 2 is shown below:

NO3+NO2→N2O5 \text{NO}_3 + \text{NO}_2 \rightarrow \text{N}_2\text{O}_5 NO3​+NO2​→N2​O5​

Suggest the equation for Step 1 and determine the rate equation for this overall reaction.

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Rates, equilibrium and pH Questions

  1. A Level
  2. /Chemistry
  3. /Rates, equilibrium and pH