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Rates, equilibrium and pH

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Question 35

This question is about weak acids and buffer solutions.

Glycolic acid, CH2(OH)COOH\text{CH}_2(\text{OH})\text{COOH}CH2​(OH)COOH, is a weak monobasic acid.

a.

Explain what is meant by the term weak monobasic acid.

[2]
b.

A buffer solution is prepared by dissolving 0.800 g0.800\text{ g}0.800 g of sodium hydroxide, NaOH\text{NaOH}NaOH, in 250.0 cm3250.0\text{ cm}^3250.0 cm3 of 0.240 mol dm−30.240\text{ mol dm}^{-3}0.240 mol dm−3 glycolic acid.

This buffer solution has a pH of 3.533.533.53 at 25∘C25^\circ\text{C}25∘C.

Calculate the acid dissociation constant, KaK_aKa​, of glycolic acid at 25∘C25^\circ\text{C}25∘C.

Assume that the volume of the solution remains constant at 250.0 cm3250.0\text{ cm}^3250.0 cm3 when the sodium hydroxide is dissolved. Give your answer to 3 significant figures.

Ka=K_a = Ka​= ........................................ mol dm−3\text{mol dm}^{-3}mol dm−3

[6]
c.

When a small volume of water is added to this buffer solution, the pH does not change.

Explain why the pH does not change.

[2]

Rates, equilibrium and pH Questions

  1. A Level
  2. /Chemistry
  3. /Rates, equilibrium and pH