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Thermodynamics (A-level only)

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Question 19
a.

Write an equation, including state symbols, to represent the process that occurs when the enthalpy of solution of strontium chloride, SrCl2\text{SrCl}_2SrCl2​, is measured.

[1]
b.

Table 1 shows some thermodynamic data.

Table 1

Process / QuantityEnthalpy change / kJ mol−1\text{kJ mol}^{-1}kJ mol−1
Enthalpy of lattice dissociation of SrCl2\text{SrCl}_2SrCl2​+2150+2150+2150
Enthalpy of hydration of Sr2+(g)\text{Sr}^{2+}(g)Sr2+(g)−1445-1445−1445
Enthalpy of hydration of Cl−(g)\text{Cl}^-(g)Cl−(g)−363-363−363

Use the data in Table 1 to calculate the value for the enthalpy of solution of strontium chloride.

[2]
c.

The enthalpy of hydration of Be2+(g)\text{Be}^{2+}(g)Be2+(g) is −2494 kJ mol−1-2494\text{ kJ mol}^{-1}−2494 kJ mol−1.

Suggest why the enthalpy of hydration for Be2+(g)\text{Be}^{2+}(g)Be2+(g) is significantly more exothermic than that of Sr2+(g)\text{Sr}^{2+}(g)Sr2+(g).

[2]

Thermodynamics (A-level only) Questions

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