The lattice enthalpy of an ionic compound can be determined experimentally using a Born–Haber cycle, or calculated theoretically using a perfect ionic model.
Which of the following metal halides is expected to show the greatest percentage difference between its experimental and theoretical lattice enthalpy values?
MgCl2\text{MgCl}_2MgCl2
BaI2\text{BaI}_2BaI2
MgI2\text{MgI}_2MgI2
BaCl2\text{BaCl}_2BaCl2
27 exam-style questions on AQA A Level Chemistry Thermodynamics (A-level only), covering Born–Haber cycles (A-level only) and Gibbs free-energy change, $\Delta G$ , and entropy change, $\Delta S$ (A-level only). Each one has a worked solution and a mark scheme showing where the marks go.