Properties of plastics
Definition
Biodegradable
Able to be broken down naturally by microorganisms such as bacteria and fungi.
Definition
Non-biodegradable
Not able to be broken down by microorganisms, so the material stays in the environment for a very long time.
- Plastics are used for packaging, bottles, bags and toys because of a set of very useful properties.
- Unreactive: most plastics do not react with water, air, acids or the food and drink they hold.
- Durable: plastics are strong, hard-wearing and do not rot or rust, so they last for a very long time.
- Low density: plastics are light for their size, and many plastic items float on water.
- Non-biodegradable: bacteria and fungi cannot break plastics down, so plastics do not decay in the environment.
- Plastics are non-biodegradable because their long chains of carbon atoms, held together by strong covalent bonds, cannot be digested by microorganisms.
- Cheap: plastics are cheap to make in huge amounts, so many items, such as drinks bottles and carrier bags, are used once and thrown away.
Example
An apple core and a plastic bottle
- Picture an apple core and a plastic drinks bottle dropped in the same hedge in the same week.
- The apple core is biodegradable, so bacteria and fungi break it down within a few weeks.
- The bottle is non-biodegradable, so it can still be there, almost unchanged, hundreds of years later.
- The bottle also stays whole because it is unreactive, so rain and air do not attack it.
Why disposal is a problem
- The same properties that make plastics useful make plastic waste hard to get rid of.
- Because plastics are unreactive and non-biodegradable, discarded plastic does not rot away, so it persists in the environment for hundreds of years.
- Because plastics are durable, every item ever thrown away is still waste, so the total amount of plastic waste keeps building up.
- Because plastics have a low density, light waste such as bags and wrappers is easily blown by the wind or carried by water, spreading litter far from where it was dropped.
- Because plastics are cheap and often used only once, very large amounts of plastic waste are produced every day.
- Most plastic waste ends up in one of three places, and each one causes its own environmental challenge.
- It is buried in a landfill site.
- It escapes as litter and accumulates in the oceans.
- It is burned, which can release toxic gases.
Landfill sites
- A landfill site is a large hole in the ground where waste is tipped and then buried.
- Plastic waste in landfill does not biodegrade, so it takes up space for hundreds of years instead of breaking down.
- Plastic items are bulky for their mass, because of their low density, so they fill landfill sites quickly.
- As existing sites fill up, new land has to be found for more landfill sites.
- This land can no longer be used for farming, housing or wildlife habitats.
- Digging new sites destroys the habitats of plants and animals.
- Some of the chemicals added to plastics can slowly leak out of buried waste into the soil and groundwater.
Plastics in the oceans
- Plastic litter that is not collected is washed into drains and rivers, or blown by the wind, and much of it ends up in the sea.
- Because many plastics have a low density, they float and are carried long distances by ocean currents.
- Currents sweep the floating waste together, so huge amounts accumulate in certain areas of the oceans.
- The plastic does not biodegrade, so the amount in the oceans keeps increasing year after year.
- Sunlight and waves break large items into smaller and smaller pieces called microplastics, but these pieces do not disappear.
- Ocean plastic harms marine animals in several ways.
- Animals such as seals, turtles and seabirds become trapped or tangled in plastic nets, rings and bags, which can injure or drown them.
- Animals mistake plastic for food, for example turtles swallow floating bags that look like jellyfish.
- Swallowed plastic fills an animal's stomach but cannot be digested, so the animal may starve.
- Microplastics are eaten by small sea creatures and pass along food chains, including into fish that people eat.
Burning plastics
- Burning plastic waste, called incineration, reduces the amount of solid waste that has to go to landfill.
- The thermal energy released by burning can be used to generate electricity.
- However, burning plastics produces toxic gases that pollute the air.
- Carbon monoxide forms when plastics burn in a limited supply of air, by incomplete combustion.
- Carbon monoxide is toxic because it combines with haemoglobin in red blood cells and stops the blood carrying oxygen.
- Plastics that contain chlorine, such as PVC, release hydrogen chloride, a toxic and acidic gas.
- Burning also releases soot (carbon particles), which damages the lungs.
- Burning plastics also releases large amounts of carbon dioxide, a greenhouse gas that adds to climate change.
Example
Burning poly(ethene)
- Poly(ethene) is made only of carbon and hydrogen, so it burns like a large alkane.
- Each section made from one ethene unit, -CH2-CH2-\text{-CH}_2\text{-CH}_2\text{-}-CH2-CH2-, contains two carbon atoms and four hydrogen atoms.
- In plenty of air, complete combustion gives carbon dioxide and water.
- In a limited supply of air, incomplete combustion gives the toxic gas carbon monoxide instead.
- Both equations balance: 2n2n2n carbon atoms and 4n4n4n hydrogen atoms appear on each side, and the oxygen atoms match the products.
Common Mistake
- Do not write that plastics "break down eventually" in landfill, because they are non-biodegradable and stay there for hundreds of years.
- Do not describe carbon dioxide as a toxic gas, because its problem is that it is a greenhouse gas.
- Do not write only "burning plastics causes pollution", because you need to name a toxic gas such as carbon monoxide or hydrogen chloride.
- Do not confuse biodegradable with recyclable, because a plastic can be recycled even though it is not biodegradable.
Exam technique
Linking properties to problems
- For "describe how the properties of plastics affect their disposal", state the property and then its consequence, joined by "so" or "because".
- A strong answer reads: "plastics are non-biodegradable, so they are not broken down by microorganisms and remain in landfill sites for a very long time".
- For ocean pollution, give the harm to living things, such as animals swallowing plastic or becoming trapped in it.
- For burning, name the gas and say it is toxic, rather than just writing "fumes" or "smoke".
Self review
- What does non-biodegradable mean?
- Why does plastic waste in landfill take up space for a very long time?
- Why does so much plastic waste float and build up in the oceans?
- Give two ways that ocean plastic harms marine animals.
- Name two toxic gases that can form when plastics are burned.