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11.8.2 Properties, disposal and environmental impact of plastics

Properties of plastics

Definition

Biodegradable

Able to be broken down naturally by microorganisms such as bacteria and fungi.

Definition

Non-biodegradable

Not able to be broken down by microorganisms, so the material stays in the environment for a very long time.

  1. Plastics are used for packaging, bottles, bags and toys because of a set of very useful properties.
  2. Unreactive: most plastics do not react with water, air, acids or the food and drink they hold.
  3. Durable: plastics are strong, hard-wearing and do not rot or rust, so they last for a very long time.
  4. Low density: plastics are light for their size, and many plastic items float on water.
  5. Non-biodegradable: bacteria and fungi cannot break plastics down, so plastics do not decay in the environment.
    1. Plastics are non-biodegradable because their long chains of carbon atoms, held together by strong covalent bonds, cannot be digested by microorganisms.
  6. Cheap: plastics are cheap to make in huge amounts, so many items, such as drinks bottles and carrier bags, are used once and thrown away.
Example

An apple core and a plastic bottle

  • Picture an apple core and a plastic drinks bottle dropped in the same hedge in the same week.
  • The apple core is biodegradable, so bacteria and fungi break it down within a few weeks.
  • The bottle is non-biodegradable, so it can still be there, almost unchanged, hundreds of years later.
  • The bottle also stays whole because it is unreactive, so rain and air do not attack it.

Why disposal is a problem

  1. The same properties that make plastics useful make plastic waste hard to get rid of.
  2. Because plastics are unreactive and non-biodegradable, discarded plastic does not rot away, so it persists in the environment for hundreds of years.
  3. Because plastics are durable, every item ever thrown away is still waste, so the total amount of plastic waste keeps building up.
  4. Because plastics have a low density, light waste such as bags and wrappers is easily blown by the wind or carried by water, spreading litter far from where it was dropped.
  5. Because plastics are cheap and often used only once, very large amounts of plastic waste are produced every day.
  6. Most plastic waste ends up in one of three places, and each one causes its own environmental challenge.
    1. It is buried in a landfill site.
    2. It escapes as litter and accumulates in the oceans.
    3. It is burned, which can release toxic gases.

Landfill sites

  1. A landfill site is a large hole in the ground where waste is tipped and then buried.
  2. Plastic waste in landfill does not biodegrade, so it takes up space for hundreds of years instead of breaking down.
  3. Plastic items are bulky for their mass, because of their low density, so they fill landfill sites quickly.
  4. As existing sites fill up, new land has to be found for more landfill sites.
    1. This land can no longer be used for farming, housing or wildlife habitats.
    2. Digging new sites destroys the habitats of plants and animals.
  5. Some of the chemicals added to plastics can slowly leak out of buried waste into the soil and groundwater.

Plastics in the oceans

  1. Plastic litter that is not collected is washed into drains and rivers, or blown by the wind, and much of it ends up in the sea.
  2. Because many plastics have a low density, they float and are carried long distances by ocean currents.
  3. Currents sweep the floating waste together, so huge amounts accumulate in certain areas of the oceans.
  4. The plastic does not biodegrade, so the amount in the oceans keeps increasing year after year.
  5. Sunlight and waves break large items into smaller and smaller pieces called microplastics, but these pieces do not disappear.
  6. Ocean plastic harms marine animals in several ways.
    1. Animals such as seals, turtles and seabirds become trapped or tangled in plastic nets, rings and bags, which can injure or drown them.
    2. Animals mistake plastic for food, for example turtles swallow floating bags that look like jellyfish.
    3. Swallowed plastic fills an animal's stomach but cannot be digested, so the animal may starve.
    4. Microplastics are eaten by small sea creatures and pass along food chains, including into fish that people eat.

Burning plastics

  1. Burning plastic waste, called incineration, reduces the amount of solid waste that has to go to landfill.
  2. The thermal energy released by burning can be used to generate electricity.
  3. However, burning plastics produces toxic gases that pollute the air.
    1. Carbon monoxide forms when plastics burn in a limited supply of air, by incomplete combustion.
    2. Carbon monoxide is toxic because it combines with haemoglobin in red blood cells and stops the blood carrying oxygen.
    3. Plastics that contain chlorine, such as PVC, release hydrogen chloride, a toxic and acidic gas.
    4. Burning also releases soot (carbon particles), which damages the lungs.
  4. Burning plastics also releases large amounts of carbon dioxide, a greenhouse gas that adds to climate change.
Example

Burning poly(ethene)

  • Poly(ethene) is made only of carbon and hydrogen, so it burns like a large alkane.
  • Each section made from one ethene unit, -CH2-CH2-\text{-CH}_2\text{-CH}_2\text{-}-CH2​-CH2​-, contains two carbon atoms and four hydrogen atoms.
  • In plenty of air, complete combustion gives carbon dioxide and water.
[−CH2−CH2−]n+3n O2→2n CO2+2n H2O \left[-\text{CH}_2-\text{CH}_2-\right]_n + 3n\,\text{O}_2 \rightarrow 2n\,\text{CO}_2 + 2n\,\text{H}_2\text{O} [−CH2​−CH2​−]n​+3nO2​→2nCO2​+2nH2​O
  • In a limited supply of air, incomplete combustion gives the toxic gas carbon monoxide instead.
[−CH2−CH2−]n+2n O2→2n CO+2n H2O \left[-\text{CH}_2-\text{CH}_2-\right]_n + 2n\,\text{O}_2 \rightarrow 2n\,\text{CO} + 2n\,\text{H}_2\text{O} [−CH2​−CH2​−]n​+2nO2​→2nCO+2nH2​O
  • Both equations balance: 2n2n2n carbon atoms and 4n4n4n hydrogen atoms appear on each side, and the oxygen atoms match the products.
Common Mistake
  • Do not write that plastics "break down eventually" in landfill, because they are non-biodegradable and stay there for hundreds of years.
  • Do not describe carbon dioxide as a toxic gas, because its problem is that it is a greenhouse gas.
  • Do not write only "burning plastics causes pollution", because you need to name a toxic gas such as carbon monoxide or hydrogen chloride.
  • Do not confuse biodegradable with recyclable, because a plastic can be recycled even though it is not biodegradable.
Exam technique

Linking properties to problems

  • For "describe how the properties of plastics affect their disposal", state the property and then its consequence, joined by "so" or "because".
  • A strong answer reads: "plastics are non-biodegradable, so they are not broken down by microorganisms and remain in landfill sites for a very long time".
  • For ocean pollution, give the harm to living things, such as animals swallowing plastic or becoming trapped in it.
  • For burning, name the gas and say it is toxic, rather than just writing "fumes" or "smoke".
Self review
  • What does non-biodegradable mean?
  • Why does plastic waste in landfill take up space for a very long time?
  • Why does so much plastic waste float and build up in the oceans?
  • Give two ways that ocean plastic harms marine animals.
  • Name two toxic gases that can form when plastics are burned.
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11.8.2 Properties, disposal and environmental impact of plastics Revision Guide

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Revision notes for CIE IGCSE Chemistry 11.8.2 Properties, disposal and environmental impact of plastics: explanations and worked examples.

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