Trends in a group
Definition
Trend
A gradual change in a property, in one overall direction, from one element to the next down or up a group.
- A trend is a gradual change in a property, in one overall direction, as you move from element to element down or up a group.
- Elements in a group have the same number of outer-shell electrons, but each element has one more occupied shell than the element above it.
- Because the change from one element to the next is always the same kind of change, properties tend to change steadily down a group rather than randomly.
- Properties that often show a trend include melting point, boiling point, density, atomic radius and reactivity.
- A property may increase down a group, decrease down a group, or show no clear trend.
- A property that increases down a group must decrease up the same group, so the direction you read in always matters.
- Questions often give you data for a group you have not studied, such as Group II or Group VI, and expect you to find the trend from that information alone.
Reading trends from data
- Put the elements in order: list them from the top of the group to the bottom, which is the order of increasing proton number.
- Read one property at a time: follow the values for a single property in that order.
- Compare the ends: compare the value for the first element with the value for the last element to find the overall direction.
- Check the middle: confirm that the values in between move in the same direction.
- Treat each property separately: one property can increase down a group while another property decreases down the same group.
- Use descriptions as well as numbers: words such as "reacts slowly", "reacts quickly" and "reacts violently" form an ordered scale, so they show a trend in reactivity just as numbers do.
- Read charts in the same way: in a bar chart, the elements are usually placed along the horizontal axis in group order, so you read the heights of the bars from left to right.
Example
A numerical trend in Group VI
- The melting points of four Group VI elements, from the top of the group, are oxygen −218 ∘C-218\ ^\circ\text{C}−218 ∘C, sulfur 115 ∘C115\ ^\circ\text{C}115 ∘C, selenium 221 ∘C221\ ^\circ\text{C}221 ∘C and tellurium 450 ∘C450\ ^\circ\text{C}450 ∘C.
- The first value is the lowest and the last value is the highest.
- Every value in between is higher than the one before it.
- The trend is that melting point increases down Group VI.
Example
A descriptive trend in Group II
- Four Group II metals are added to dilute hydrochloric acid of the same concentration.
- Magnesium fizzes steadily, calcium fizzes rapidly, strontium fizzes very rapidly and barium reacts violently.
- The descriptions become more vigorous from magnesium to barium.
- The trend is that reactivity increases down Group II.
Writing a complete trend statement
- A complete statement names the property, the direction of change and the direction in the group.
- "The melting point increases down the group" is complete, because it gives all three parts.
- "It increases" is incomplete, because it does not say which property changes or in which direction you are reading.
- Use down the group when reading from top to bottom and up the group when reading from bottom to top.
- When a question asks you to use the data, quote values with their units as evidence, such as "from 115 ∘C115\ ^\circ\text{C}115 ∘C for sulfur to 450 ∘C450\ ^\circ\text{C}450 ∘C for tellurium".
- Comparative words such as higher, lower, denser and more reactive are the clearest way to compare two elements in the same group.
- A change along a period is not a group trend, so only describe the elements in the column you have been given.
Anomalies and unclear patterns
Definition
Anomalous value
A value that does not fit the pattern shown by the rest of the data.
- An anomalous value is a value that does not fit the pattern shown by the rest of the data.
- If one value breaks an otherwise steady trend, describe the overall trend and name the element whose value does not fit.
- Do not ignore an anomalous value, and do not let one odd value hide the trend shown by all the others.
- If the values rise and fall with no overall direction, state that the property shows no clear trend.
- A trend does not need equal steps between neighbouring elements, so values of 555, 999, 202020 and 222222 still show a steady increase.
Example
A trend with an anomaly in Group II
- The melting points of the Group II metals, from the top of the group, are beryllium 1287 ∘C1287\ ^\circ\text{C}1287 ∘C, magnesium 650 ∘C650\ ^\circ\text{C}650 ∘C, calcium 842 ∘C842\ ^\circ\text{C}842 ∘C, strontium 777 ∘C777\ ^\circ\text{C}777 ∘C and barium 727 ∘C727\ ^\circ\text{C}727 ∘C.
- Beryllium has the highest value and barium has one of the lowest, so the overall direction is downwards.
- Calcium, strontium and barium each have a lower melting point than the element above them.
- Magnesium does not fit, because its melting point is lower than that of calcium, the element below it.
- The trend is that melting point generally decreases down Group II, with magnesium as the anomalous value.
Estimating a missing value
- When a trend is steady, a missing value lies between the values of the elements directly above and below it.
- For an element at the bottom of the group, continue the pattern in the same direction.
- Keep the size of an estimated step similar to the steps already shown in the data.
- An estimate does not need to match the real value exactly, as long as it fits the trend shown by the data.
Example
Estimating the boiling point of krypton
- The boiling points of four noble gases are helium −269 ∘C-269\ ^\circ\text{C}−269 ∘C, neon −246 ∘C-246\ ^\circ\text{C}−246 ∘C, argon −186 ∘C-186\ ^\circ\text{C}−186 ∘C and xenon −108 ∘C-108\ ^\circ\text{C}−108 ∘C.
- Each value is higher than the one above it, so boiling point increases down the group.
- Krypton sits between argon and xenon, so its boiling point must lie between −186 ∘C-186\ ^\circ\text{C}−186 ∘C and −108 ∘C-108\ ^\circ\text{C}−108 ∘C.
- A sensible estimate is about −150 ∘C-150\ ^\circ\text{C}−150 ∘C, and the measured value is −153 ∘C-153\ ^\circ\text{C}−153 ∘C.
Exam technique
Answering trend questions
- Check whether the question asks about the change down or up the group before you write the direction.
- When a question says "use the information", base your answer only on the data given, even if the group is one you have not met before.
- When several properties are listed, write a separate trend statement for each one and name the property every time.
Self review
- What is meant by a trend in a group?
- In what order should you list the elements before reading a trend from a table?
- What three parts does a complete trend statement contain?
- What should you write if one value does not fit the pattern shown by the others?
- How would you estimate a missing value for an element in the middle of a group?