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8.1.2 Identifying trends in groups

Trends in a group

Definition

Trend

A gradual change in a property, in one overall direction, from one element to the next down or up a group.

  1. A trend is a gradual change in a property, in one overall direction, as you move from element to element down or up a group.
  2. Elements in a group have the same number of outer-shell electrons, but each element has one more occupied shell than the element above it.
  3. Because the change from one element to the next is always the same kind of change, properties tend to change steadily down a group rather than randomly.
  4. Properties that often show a trend include melting point, boiling point, density, atomic radius and reactivity.
  5. A property may increase down a group, decrease down a group, or show no clear trend.
  6. A property that increases down a group must decrease up the same group, so the direction you read in always matters.
  7. Questions often give you data for a group you have not studied, such as Group II or Group VI, and expect you to find the trend from that information alone.

Reading trends from data

  1. Put the elements in order: list them from the top of the group to the bottom, which is the order of increasing proton number.
  2. Read one property at a time: follow the values for a single property in that order.
  3. Compare the ends: compare the value for the first element with the value for the last element to find the overall direction.
  4. Check the middle: confirm that the values in between move in the same direction.
  5. Treat each property separately: one property can increase down a group while another property decreases down the same group.
  6. Use descriptions as well as numbers: words such as "reacts slowly", "reacts quickly" and "reacts violently" form an ordered scale, so they show a trend in reactivity just as numbers do.
  7. Read charts in the same way: in a bar chart, the elements are usually placed along the horizontal axis in group order, so you read the heights of the bars from left to right.
Example

A numerical trend in Group VI

  • The melting points of four Group VI elements, from the top of the group, are oxygen −218 ∘C-218\ ^\circ\text{C}−218 ∘C, sulfur 115 ∘C115\ ^\circ\text{C}115 ∘C, selenium 221 ∘C221\ ^\circ\text{C}221 ∘C and tellurium 450 ∘C450\ ^\circ\text{C}450 ∘C.
  • The first value is the lowest and the last value is the highest.
  • Every value in between is higher than the one before it.
  • The trend is that melting point increases down Group VI.
Example

A descriptive trend in Group II

  • Four Group II metals are added to dilute hydrochloric acid of the same concentration.
  • Magnesium fizzes steadily, calcium fizzes rapidly, strontium fizzes very rapidly and barium reacts violently.
  • The descriptions become more vigorous from magnesium to barium.
  • The trend is that reactivity increases down Group II.

Writing a complete trend statement

  1. A complete statement names the property, the direction of change and the direction in the group.
  2. "The melting point increases down the group" is complete, because it gives all three parts.
  3. "It increases" is incomplete, because it does not say which property changes or in which direction you are reading.
  4. Use down the group when reading from top to bottom and up the group when reading from bottom to top.
  5. When a question asks you to use the data, quote values with their units as evidence, such as "from 115 ∘C115\ ^\circ\text{C}115 ∘C for sulfur to 450 ∘C450\ ^\circ\text{C}450 ∘C for tellurium".
  6. Comparative words such as higher, lower, denser and more reactive are the clearest way to compare two elements in the same group.
  7. A change along a period is not a group trend, so only describe the elements in the column you have been given.

Anomalies and unclear patterns

Definition

Anomalous value

A value that does not fit the pattern shown by the rest of the data.

  1. An anomalous value is a value that does not fit the pattern shown by the rest of the data.
  2. If one value breaks an otherwise steady trend, describe the overall trend and name the element whose value does not fit.
  3. Do not ignore an anomalous value, and do not let one odd value hide the trend shown by all the others.
  4. If the values rise and fall with no overall direction, state that the property shows no clear trend.
  5. A trend does not need equal steps between neighbouring elements, so values of 555, 999, 202020 and 222222 still show a steady increase.
Example

A trend with an anomaly in Group II

  • The melting points of the Group II metals, from the top of the group, are beryllium 1287 ∘C1287\ ^\circ\text{C}1287 ∘C, magnesium 650 ∘C650\ ^\circ\text{C}650 ∘C, calcium 842 ∘C842\ ^\circ\text{C}842 ∘C, strontium 777 ∘C777\ ^\circ\text{C}777 ∘C and barium 727 ∘C727\ ^\circ\text{C}727 ∘C.
  • Beryllium has the highest value and barium has one of the lowest, so the overall direction is downwards.
  • Calcium, strontium and barium each have a lower melting point than the element above them.
  • Magnesium does not fit, because its melting point is lower than that of calcium, the element below it.
  • The trend is that melting point generally decreases down Group II, with magnesium as the anomalous value.

Estimating a missing value

  1. When a trend is steady, a missing value lies between the values of the elements directly above and below it.
  2. For an element at the bottom of the group, continue the pattern in the same direction.
  3. Keep the size of an estimated step similar to the steps already shown in the data.
  4. An estimate does not need to match the real value exactly, as long as it fits the trend shown by the data.
Example

Estimating the boiling point of krypton

  • The boiling points of four noble gases are helium −269 ∘C-269\ ^\circ\text{C}−269 ∘C, neon −246 ∘C-246\ ^\circ\text{C}−246 ∘C, argon −186 ∘C-186\ ^\circ\text{C}−186 ∘C and xenon −108 ∘C-108\ ^\circ\text{C}−108 ∘C.
  • Each value is higher than the one above it, so boiling point increases down the group.
  • Krypton sits between argon and xenon, so its boiling point must lie between −186 ∘C-186\ ^\circ\text{C}−186 ∘C and −108 ∘C-108\ ^\circ\text{C}−108 ∘C.
  • A sensible estimate is about −150 ∘C-150\ ^\circ\text{C}−150 ∘C, and the measured value is −153 ∘C-153\ ^\circ\text{C}−153 ∘C.
Exam technique

Answering trend questions

  • Check whether the question asks about the change down or up the group before you write the direction.
  • When a question says "use the information", base your answer only on the data given, even if the group is one you have not met before.
  • When several properties are listed, write a separate trend statement for each one and name the property every time.
Self review
  • What is meant by a trend in a group?
  • In what order should you list the elements before reading a trend from a table?
  • What three parts does a complete trend statement contain?
  • What should you write if one value does not fit the pattern shown by the others?
  • How would you estimate a missing value for an element in the middle of a group?
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